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Record W4417009512 · doi:10.1021/acsomega.5c10061

Predictive <i>N</i> -Glycan Signatures of Severe Traumatic Brain Injury in Biofluids Using LC–MS/MS

2025· article· en· W4417009512 on OpenAlexaff
Joy Solomon, Sherifdeen Onigbinde, Moyinoluwa Adeniyi, Oluwatosin Daramola, Cristian D. Gutierrez Reyes, Mojibola Fowowe, Md Mostofa Al Amin Bhuiyan, Judith Nwaiwu, Firas Kobeissy, Stefania Mondello, Ava M. Puccio, Yehia Mechref

Bibliographic record

VenueACS Omega · 2025
Typearticle
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicGlycosylation and Glycoproteins Research
Canadian institutionsOntario Neurotrauma Foundation
FundersNational Institute of General Medical SciencesUniversity of PittsburghUniversità degli Studi di MessinaTexas Tech UniversityMorehouse School of MedicineNational Institutes of HealthCH FoundationWelch Foundation
KeywordsTraumatic brain injuryFucosylationBiomarkerPathogenesisMultiple sclerosisGlycomicsCentral nervous systemCerebrospinal fluidDiagnostic biomarker

Abstract

fetched live from OpenAlex

High Resolution Image Download MS PowerPoint Slide Traumatic brain injury (TBI) poses a significant global health issue, frequently resulting in persistent and even lifelong cognitive and neurological impairments. Despite remarkable advances in biomarker discovery, significant challenges remain in the accurate diagnosis and prognosis of TBI. Glycosylation, an important post-translational modification of proteins and other biomolecules, plays an essential role in neuronal function and neuroinflammation. However, its contribution to the pathogenesis of TBI has been insufficiently investigated. This study examines changes in N -glycosylation patterns in serum and cerebrospinal fluid (CSF) from individuals with severe traumatic brain injury (sTBI) at various time points postinjury. Employing advanced glycomics methodologies and liquid chromatography–tandem mass spectrometry (LC–MS/MS), we identified 102 N -glycans in serum and 86 N -glycans in CSF, revealing substantial alterations in N -glycan expression, including differential expression of fucosylated and sialylated structures. Elevated fucosylation was observed in serum, whereas decreased fucosylation was found in CSF. Altered sialylation patterns were noted, suggesting glycosylation alterations in neuroinflammatory processes and possible neurodegeneration. Furthermore, our study examined N -glycans with isomeric properties. We identified several isomers that demonstrated potential as a biomarker panel reflective of TBI progression. Overall, these studies offer new insights into systemic and central nervous system-specific glycomic responses following sTBI and emphasize the potential of glycan-based biomarkers for monitoring specific changes as TBI progresses, which could be a possible target for enhanced TBI therapy and enhanced prognosis.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.028
Threshold uncertainty score0.539

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.305
Teacher spread0.291 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2025
Admission routes1
Has abstractyes

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