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Record W4417049965 · doi:10.2138/am-2025-10072

Grahampearsonite, Ca2P2O7, a new mineral found in a super-deep diamond from Juína, Brazil

2025· article· en· W4417049965 on OpenAlexaboutno aff
Yanjuan Wang, Fabrizio Nestola, Maxwell C. Day, Tiago Jalowitzki, Fernanda Gervasoni, Daniel Grings Cedeño, Sebastião William da Silva, Reinhardt A. Fuck, Jacopo Nava, Lisa Santello, Martha G. Pamato, Davide Novella, Francesca Innocenzi, Andrea Curtolo, Mattia La Fortezza, Kai Qu

Bibliographic record

VenueAmerican Mineralogist · 2025
Typearticle
Languageen
FieldMaterials Science
TopicCrystal Structures and Properties
Canadian institutionsnot available
FundersUniversità degli Studi di PadovaChinese Academy of Geological SciencesConselho Nacional de Desenvolvimento Científico e TecnológicoEuropean Commission
KeywordsDiamondMineralCalciteTetragonal crystal systemPhosphorusCrystal (programming language)Decomposition

Abstract

fetched live from OpenAlex

Abstract Grahampearsonite, ideally Ca2P2O7, is a new mineral (IMA 2025-017) that was found in a multi-phase inclusion in a super-deep diamond (sample RV43) from the Chapadão plateau, Mato Grosso, Brazil. The new mineral is closely associated with tuite and with other mineral inclusions in the host diamond (that are not in direct contact with grahampearsonite) including larnite, merrillite, apatite, diopside, ilmenite, magnetite, calcite, and an unidentified phosphate phase. X-ray diffraction analyses, performed directly on the inclusion while still entrapped in the diamond, revealed a tetragonal crystal structure (space group P41), with unit-cell parameters a = 6.6966(16) Å, c = 24.145(11) Å, and V = 1082.8(6) Å3. The identification of grahampearsonite as the natural analog of synthetic β-Ca2P2O7 is strongly supported by micro-Raman, FTIR, crystal chemical, and X-ray diffraction data. The occurrence of grahampearsonite and tuite in a super-deep diamond indicates that grahampearsonite could be related to the decomposition of tuite and may provide new insights into the Earth’s deep phosphorus reservoir and the crust-mantle phosphorus cycle. The new mineral honors Graham D. Pearson, University of Alberta, for his outstanding contributions to diamond research.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.827
Threshold uncertainty score0.986

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.262
Teacher spread0.252 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2025
Admission routes1
Has abstractyes

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