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Record W586611340

FIFTY YEARS ON - LOOKING BACK AT DEVELOPMENTS IN METHODS OF BLOOD- AND BREATH-ALCOHOL ANALYSIS

2000· article· en· W586611340 on OpenAlexaboutno aff
Alan Wayne Jones

Bibliographic record

VenueProceedings International Council on Alcohol, Drugs and Traffic Safety Conference · 2000
Typearticle
Languageen
FieldEngineering
TopicAdvanced Chemical Sensor Technologies
Canadian institutionsnot available
Fundersnot available
KeywordsAlcoholBreath gas analysisGas chromatographyChemistryChromatographyEthanolAlcohol dehydrogenaseBreath testAlcohol oxidationBlood alcoholPoison controlMedicineBiochemistryInjury preventionEnvironmental healthInternal medicine
DOInot available

Abstract

fetched live from OpenAlex

Exactly 50 years ago at the T-1950 conference in Stockholm, a new principle was introduced for measuring alcohol in biological specimens. This involved the oxidation of ethanol with an enzyme called alcohol dehydrogenase (ADH), which had been extracted and purified from horse liver. The ADH method was more sensitive and selective for measuring ethanol than the wet-chemistry oxidation procedures used during the first half of the century. Breath tests for alcohol were given a boost when Borkenstein developed the Breathalyzer in 1954. Breath testing for alcohol influence became widely used for traffic law enforcement purposes in USA, Canada, and Australia. In European countries blood and urine were the preferred specimens for forensic alcohol analysis and by the early 1960s the method of gas chromatography (GC) appeared including the headspace sampling technique, which was perfect for analyzing volatile substances in body fluids. Interest in Europe shifted towards evidential breath-alcohol testing in the 1980s, which coincided with the introduction of new analytical technology for sampling and analysis of breath, such as compact infrared (IR) spectrometers controlled by microprocessors. In the 1970s, electrochemical oxidation of alcohol with fuel cell devices became popular and these were incorporated into hand-held instruments suitable for roadside screening of motorists. Recent improvements in this kind of technology have meant that fuel cells are being used for evidential breath-alcohol testing. Whether breath-alcohol devices utilizing gas chromatography and mass spectrometry (GC-MS) or Fourier transform infrared spectrometry (FTIR) will emerge to provide the ultimate way of identifying ethanol in blood and breath samples for forensic purposes remains to be seen. One goal for the new millennium, at least in some countries, seems to be the use of evidential breath-alcohol testing at the roadside. This saves much time and resources for the police and also reduces the number of false-positive roadside alcohol screening tests. For the covering abstract see ITRD E106992.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Other design · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.840
Threshold uncertainty score0.928

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.037
GPT teacher head0.278
Teacher spread0.241 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designOther design
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2000
Admission routes1
Has abstractyes

Explore more

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