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Record W64519849 · doi:10.2166/ws.2002.0015

UV/H2O2-treatment: the ultimate solution for pesticide control and disinfection

2002· article· en· W64519849 on OpenAlex
J.C. Kruithof, Peer C. Kamp, Miodrag Belosevic

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
aboutThe title or abstract carries a Canadian signal from the geographic lexicon.

Bibliographic record

VenueWater Science & Technology Water Supply · 2002
Typearticle
Languageen
FieldEnvironmental Science
TopicWater Treatment and Disinfection
Canadian institutionsUniversity of Alberta
Fundersnot available
KeywordsPesticideBromateChemistryAtrazineWater treatmentEnvironmental chemistryTylosinHydrogen peroxideDegradation (telecommunications)ContaminationPesticide degradationPulp and paper industryEnvironmental scienceEnvironmental engineeringBromideAgronomyOrganic chemistry

Abstract

fetched live from OpenAlex

Because of high contents of pesticides and micro-organisms in IJssel Lake water N.V. PWN Water Supply Company North Holland (PWN) was compelled to implement multiple barriers against these contaminants at their surface water treatment plants at Heemskerk and Andijk. For degradation of pesticides advanced oxidation was pursued. After thorough studies O3/H2O2-treatment was rejected in view of bromate formation. Subsequently application of UV/H2O2-treatment was pursued. UV-photolysis shows a selective pesticide degradation. Conversion using an electric energy of 1 kWh/m3 varies from 18% for trichloroacetic acid to 70% for atrazine. UV/H2O2-treatment gives a much more aselective pesticide degradation. For a combination of an electric energy of 1 kWh/m3 and 15 g/m3 H2O2 most pesticides can be degraded by more than 80%. Formation of harmful by-products proved to be insignificant. In the range of 0.1-2.5 kWh/m3 electric energy and 0-25 g/m3 H2O2 bromate formation is absent, while metabolite formation is insignificant. AOC-formation is found up to 140 μg/l. Therefore AOC and residual H2O2 must be removed in a following treatment step. GAC-filtration showed very reliable results. Application of UV/H2O2-treatment for pesticide control with an electric energy of 1 kWh/m3 goes together with an average UV-dose of 2,000 mJ/cm2. This dose is about 50 times as high as applied in conventional UV-disinfection. As expected E. coli and (after spiking) spores of sulphite reducing Clostridia are inactivated completely. In addition orientating experiments have been carried out with an UV-dose of 100 mJ/cm2. Inactivation of MS-2 phages amounted to 2.7 log, Bacillus spores inactivation to 3.4 log, while Cryptosporidium inactivation was complete (>3 log). Additional data are gathered together with the University of Alberta. In view of the very promising results, application of UV/H2O2-treatment will be pursued for full scale application at both the Heemskerk plant for organic contaminant control and the Andijk plant for both organic contaminant control and disinfection.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.444
Threshold uncertainty score0.983

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0010.002
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.203
Teacher spread0.195 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it