Water column CO2 system measurements collected during the 2016 National Oceanic and Atmospheric Administration West Coast Ocean Acidification survey (NOAA WCOA2016) from California to British Columbia
Bibliographic record
Abstract
Carbon dioxide partial pressure (pCO2) and total dissolved inorganic carbon (TCO2) measurements were made on seawater collected from 12 depths at select stations occupied during the 2016 National Oceanic and Atmospheric Administration West Coast Ocean Acidification survey (NOAA WCOA2016) from California to British Columbia. NOAA cruise data collected during this survey are available from the National Centers for Environmental Information (https://www.nodc.noaa.gov/ocads/oceans/Coastal/WCOA.html). Hakai Institute staff (Evans) collected data only during the second leg of the survey from May 24 to June 7. Information describing the cruise plan and cruise blog can be found on the NOAA Pacific Marine Environmental Laboratory (PMEL) website (https://www.pmel.noaa.gov/co2/story/2016+West+Coast+Ocean+Acidification+Cruise). Seawater sampling during this cruise was conducted using a conductivity-temperature-depth (CTD) profiler coupled with a 24-Niskin (11-L) bottle rosette. Seawater collection was concentrated in the upper 200 m at standard depths: 3 m, 10 m, 20 m, 30 m, 50 m, 80 m, 100 m, 125 m, 150 m, and 200 m. Two additional deeper depths were sampled when the water column exceeded 200 m. Additional shallow depths were sampled at the Hakai Institute’s oceanographic station QU39 (http://dx.doi.org/10.21966/1.715738). Samples were drawn from the Niskin bottles with care not to introduce bubbles into 350 mL amber glass bottles using silicone tubing, and left with 3 mL of headspace. Samples were then fixed with 200 µL of mercuric chloride and crimp-sealed with polyethylene-lined metal caps. Samples were stored in the dark and at room temperature until analysis on the Hakai Institute’s Burke-o-Lator (BoL). For detailed protocols on data processing including CO2 system determination, and quality assurance, please see Pocock et al. (2017; http://dx.doi.org/10.21966/1.521066). Final CO2 system parameters (pHT, pCO2, and aragonite saturature state) were computed using (primary) CTD temperature and salinity, and BoL determined total CO2 (TCO2) corrected using certified reference materials and alkalinity (Alk) using the carbonic acid dissociation constants of Lueker et al. (2000). Calculations were done relative to in situ pressure. Note Alk here is assumed here to consist of carbonate, bicarbonate, borate, hydroxide, and hydrogen ions; neglecting the influence of nutrients and organic acids. The effort to collect these data are part of the Hakai Institute’s directive to advance the understanding of carbon cycling in northeast Pacific coastal settings with specific emphasis on ocean acidification.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.001 |
| Meta-epidemiology (narrow) | 0.001 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.001 | 0.003 |
| Science and technology studies | 0.002 | 0.000 |
| Scholarly communication | 0.001 | 0.000 |
| Open science | 0.001 | 0.001 |
| Research integrity | 0.000 | 0.001 |
| Insufficient payload (model declined to judge) | 0.003 | 0.001 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".