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Record W6945003352 · doi:10.18739/a2jm23h6z

Dissolved Nitrogen Concentrations and Stable Isotopic Composition in The Eastern Canadian Arctic Archipelago and Baffin Bay, Legs 2a and 2b of the ArcticNet expedition, CCGS Amundsen, July 5th to August 15th 2019

2023· dataset· en· W6945003352 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

aboutThe title or abstract carries a Canadian signal from the geographic lexicon.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueUC Santa Barbara · 2023
Typedataset
Languageen
Field
Topic
Canadian institutionsnot available
Fundersnot available
KeywordsBayNitrateArcticBiogeochemical cyclePhytoplanktonδ15NNitrogenMeltwater

Abstract

fetched live from OpenAlex

Climate change is expected to alter the input of nitrogen (N) sources in the Eastern Canadian Arctic Archipelago (ECAA) and Baffin Bay due to increased discharge from glacial meltwater and permafrost thaw. Since dissolved inorganic N is generally depleted in surface waters, dissolved organic N (DON) could represent a significant N source fueling phytoplankton activity in Arctic ecosystems. Yet, few DON data for this region exist. We measured concentrations and stable isotope ratios (δ15N and δ18O) of DON and nitrate (NO3−) to investigate the sources and cycling of dissolved nitrogen in regional rivers and at the sea surface from samples collected in the ECAA and Baffin Bay. Samples were collected during Leg 2a and 2b of the ArcticNet expedition aboard the Canadian Coast Guard Ship (CCGS) Amundsen from July 5th to August 15th of 2019. The concentration and δ15N of DON were measured as in Knapp et al. (2005). Total dissolved nitrogen (TDN) was oxidized to NO3− using recrystallized persulfate followed by measurement on a NOx analyzer by chemiluminescent detection (Braman and Hendrix, 1989). The δ15N of NO3 was determined using the denitrifier method (Weigand et al., 2016). References: Braman, R. S., and Hendrix, S. A. (1989). Nanogram Nitrite and Nitrate Determination in Environmental and Biological Materials by Vanadium(III) Reduction with Chemiluminescence Detection. Analytical Chemistry, 61, 2715–2718. Knapp, A. N., Sigman, D. M., and Lipschultz, F. (2005). N isotopic composition of dissolved organic nitrogen and nitrate at the Bermuda Atlantic Time-series Study site. Global Biogeochemical Cycles, 19(1). Weigand, M. A., Foriel, J., Barnett, B., Oleynik, S., and Sigman, D. M. (2016). Updates to instrumentation and protocols for isotopic analysis of nitrate by the denitrifier method. Rapid Communications in Mass Spectrometry, 30(12), 1365-1383.).

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Dataset · Consensus signal: none
Teacher disagreement score0.704
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0010.001
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.018
GPT teacher head0.260
Teacher spread0.242 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Quick stats

Citations1
Published2023
Admission routes1
Has abstractyes

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