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Record W6980227950

Bicyclic γ-lactam lactone as chiral non-racemic intermediates: Synthesis of (+)-(1<i>S</i>, 8a<i>S</i>)-1-hydroxyindolizidine and an approach to (−)-slaframine.

2008· dissertation· en· W6980227950 on OpenAlexfundno aff

Bibliographic record

VenueoURspace (University of Regina) · 2008
Typedissertation
Languageen
FieldChemistry
TopicAsymmetric Synthesis and Catalysis
Canadian institutionsnot available
FundersFaculty of Graduate Studies and Research, University of AlbertaNatural Sciences and Engineering Research Council of Canada
KeywordsNucleofectionGestational periodTSG101DysgeusiaLiquationDiafiltrationTriacetinEmperipolesisDurvalumab
DOInot available

Abstract

fetched live from OpenAlex

L'auteur a accords une licence non exclusive permettant a Ia Bibliotheque et Archives Canada de reproduire, publier, archiver, sauvegarder, conserver, transmettre au public par telecommunication ou par ('Internet, preter, distribuer et vendre des theses partout dans le monde, a des fins commerciales ou autres, sur support microforme, papier, electronique et/ou autres formats.L'auteur conserve la propriete du droit d'auteur et des droits moraux qui protege cette these.Ni Ia these ni des extraits substantiels de celle-ci ne doivent etre imprimes ou autrement reproduits sans son autorisation.In compliance with the Canadian Privacy Act some supporting forms may have been removed from this thesis.While these forms may be included in the document page count, their removal does not represent any loss of content from the thesis. 1+1 CanadaConformement a la loi canadienne sur la protection de la vie privee, quelques formulaires secondaires ont ete enleves de cette these.Bien que ces formulaires aient inclus dans la pagination, it n'y aura aucun contenu manquant.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.007

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.215
Teacher spread0.207 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2008
Admission routes1
Has abstractno

Explore more

Same venueoURspace (University of Regina)Same topicAsymmetric Synthesis and CatalysisFrench-language works237,207