The Measurement of Atmospheric Species with Absorptions Close to the Actinic Flux Cut-Off by Active & MAX-DOAS: Chlorine Monoxide (CIO) & Sulphur Dioxide (SO2)
Bibliographic record
Abstract
The gas-phase chlorine monoxide (ClO) radical has been studied extensively for its role in catalytic stratospheric ozone depletion following the discovery of the Antarctic ozone hole in 1985. Reactive chlorine chemistry is known to occur in the troposphere as well, originating primarily from sea salt aerosols in the marine boundary layer, but direct spectroscopic observations have been limited. In this research, we endeavour to identify and quantify ClO in a mid-latitude urban atmosphere removed from a large source of salt water, using techniques of differential optical absorption spectroscopy (DOAS). In particular, we seek to determine whether this trace gas is present in any appreciable amount in ambient air during the wintertime owing to the widespread application of road salt. The study was performed at The Centre for Atmospheric Chemistry at York University in Toronto, Ontario, Canada (43.77 N, 79.50 W) using Active long-path DOAS and MAX-DOAS.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.001 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".