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Record W7024857078

Synthesis And Characterization Of Dyes And Benzimidazole-Phenols For The Study Of Electron Transfer`

2015· other· en· W7024857078 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

fundA Canadian funder is recorded on the work.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueArizona State University Library Digital Repository (Arizona State University) · 2015
Typeother
Languageen
FieldChemistry
TopicAnalytical chemistry methods development
Canadian institutionsnot available
FundersDivision of Graduate EducationDivision of Materials ResearchBasic Energy SciencesNatural Sciences and Engineering Research Council of CanadaOffice of ScienceMinisterio de Ciencia y TecnologíaConsejo Nacional de Ciencia y TecnologíaAgencia Nacional de Promoción Científica y TecnológicaUniversidad Nacional de Río CuartoU.S. Department of EnergyConsejo Nacional de Investigaciones Científicas y TécnicasMcGill UniversityArizona State UniversityChemical Sciences, Geosciences, and Biosciences DivisionSecretaría de Ciencia y Técnica, Universidad de Buenos AiresNational Science Foundation
KeywordsCharacterization (materials science)LinkerElectron transferElectron transport chainArtificial photosynthesisElectronSolar energySolar energy conversionComponent (thermodynamics)
DOInot available

Abstract

fetched live from OpenAlex

abstract: Converting solar energy into electricity is a reasonable way to ameliorate the current untenable energy situation. One way to harness solar energy is to mimic the mechanisms already present in natural photosynthesis. A key component of many artificial photosynthetic systems is the linker connecting the dye to an electrode. Studying the associated electron transport process is important for improving linker efficiency. Similarly it is important to be able to control the electron transfer to the dye from a water oxidation catalyst, and to be able to improve the lifetime of the charge separated state. Natural photosynthesis provides a blueprint for this in the tyrosine-histidine pair in photosystem II. In this work, research on these topics is described.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.739
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.001
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.183
Teacher spread0.173 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it