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Record W7043367996

Synthesis of selected fragments of the Lewis B Lewis A Tumor-Associated Carbohydrate Antigen

2021· dissertation· en· W7043367996 on OpenAlexaff

Bibliographic record

VenueThe Atrium (University of Guelph) · 2021
Typedissertation
Languageen
FieldChemistry
TopicCarbohydrate Chemistry and Synthesis
Canadian institutionsUniversity of Guelph
Fundersnot available
KeywordsCarbohydrateImmune systemAntigenTumor cellsCellAntibody
DOInot available

Abstract

fetched live from OpenAlex

Carbohydrates are the most abundant class of natural products found in living organisms. They are present on the surface of cells and play a vital role in cell recognition. It has been observed that tumor cells overexpress some oligosaccharides on their surface. These oligosaccharides have been named Tumor-Associated Carbohydrate Antigens (TACA). One TACA of interest to our research group is the LebLea heptaasaccharide, which is displayed on the surface of liver, pancreas and endometrium carcinomas. Carbohydrates are immunogenic, therefore, it is possible to design a carbohydrate-based vaccine against these tumor cells. However, an immune response against LebLea would likely result in an auto-immune response as Leb is found on healthy cells. If a fragment of LebLea is used instead, it is quite possible that an immune response is raised against LebLea while being harmless to normal healthy cells. This thesis describes the synthesis of tri- tetra- and pentasaccharide fragments of LebLea. The synthesized fragments can then be subjected to immunochemical studies to test for cross-reactivity. Successful results may lead to a potential carbohydrate based anticancer vaccine for the proposed TACA LebLea.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.004
Threshold uncertainty score0.012

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0040.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.195
Teacher spread0.186 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2021
Admission routes1
Has abstractyes

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