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Record W7043789006

Topographical Controls on Nitrous Oxide Emissions from Agricultural Fields

2023· dissertation· en· W7043789006 on OpenAlexaboutno aff

Bibliographic record

VenueThe Atrium (University of Guelph) · 2023
Typedissertation
Languageen
FieldMaterials Science
TopicEnzyme Structure and Function
Canadian institutionsnot available
Fundersnot available
KeywordsAgricultureNitrous oxideGreenhouse gasSoil waterArable landHydrology (agriculture)Agricultural landCropping
DOInot available

Abstract

fetched live from OpenAlex

Agriculture contributes 81% of global and 77% of Canadian anthropogenic nitrous oxide (N2O) emissions. Topography can intervene and accelerate emission processes by redistributing nutrients and water and creating N2O hotspots. Canada included topographical coefficient (N2Otopo) for N2O emission factor calculation for the national inventory; however, N2Otopo for Canada was quantified based on only three studies from the Prairie region. Although more than 30% of 4.9 million hectares of agricultural lands in Ontario exhibit 2 – 5% slope variations and 14.5% of lands exhibit >5% slope variation, interactions between topographical properties and N2O emissions from Ontario’s soils have not received significant attention. Owing to different climatic conditions and cropping practices, the impact of topography on N2O might be different in Ontario than Prairies leading to under- or overestimation of N2O emission. The overall objective of this study was to quantify complex interconnections among soil, topography, and N2O emissions. The specific objectives were to i) examine spatiotemporal variations in N2O emissions from different topographical positions in agricultural fields, ii) quantify direct and indirect impacts of topography on N2O, iii) identify hotspots and representative monitoring locations of N2O, and iv) quantify N2O emissions from depressions and in-field seasonal wetlands. Experiments were conducted at two agricultural fields with variable topography in Ontario over a corn-soybean rotation. Sampling points were selected using conditional Latin hypercube design using slope, elevation, wetness index, and landform classes as covariates. The concave: convex ratio of N2O emissions in Ontario was smaller (1.1) than what is being used in Canadian National Inventory (3.4). Significant correlations were observed between soil, topography, and N2O emissions (chapter 3). These correlations further helped in the quantification of the indirect impacts of topography on N2O using structural equation modeling (chapter 4). Furthermore, time stability analysis showed that 5 of 7 hotspots of N2O were in shoulder (convex) positions (chapter 5). Similarly, field zones with higher wetness index emitted higher N2O during corn and lowest during soybean season (chapter 6), suggesting different drivers of N2O emissions in different growing seasons.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.955
Threshold uncertainty score0.633

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.215
Teacher spread0.203 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2023
Admission routes1
Has abstractyes

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