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Record W7047161279

Evaluation of the Potential Impacts of Submerging the Oxidized Tailings and Adding a Cover Layer at Mine Principale

2024· dissertation· en· W7047161279 on OpenAlexaboutno aff

Bibliographic record

VenueUWSpace (University of Waterloo) · 2024
Typedissertation
Languageen
FieldPhysics and Astronomy
TopicSuperconducting and THz Device Technology
Canadian institutionsnot available
Fundersnot available
KeywordsTailingsHazardous wasteDissolutionExtraction (chemistry)GroundwaterWater tableAquifer
DOInot available

Abstract

fetched live from OpenAlex

Oxidation of sulfide minerals generates acid and forms various secondary phases including Fe(III) (oxy)hydroxide phases, jarosite, and gypsum, which can attenuate hazardous metal(loid)s by precipitation, co-precipitation, and adsorption reactions within tailings. The abandoned Cu-Ag mine at Mine Principale, Chibougamau, Québec, has three tailings impoundments (Parcs, A, B, and C) that have oxidized for more than 50 years. This project focused on Parc B, where tailings are stored to an average depth of 8.0 meters below the ground surface (mbgs). The study involved mineralogical, chemical, and microbiological analyses to evaluate the potential impacts of the proposed elevated water table (EWT) technique on the partially oxidized tailings. The EWT involves raising the water table and maintaining it above reactive tailings. Increasing the water content limits sulfide-mineral oxidation by minimizing O2 ingress into the tailings, owing to its low diffusivity in saturated media. However, the EWT can cause direct dissolution of soluble secondary phases, and also can potentially induce reducing conditions that promote microbially catalyzed reductive dissolution of Fe(III) (oxy)hydroxide phases fueled by organic C compounds. In this study, mineralogical and selective chemical extraction techniques indicate the presence of various secondary phases including Fe(III) (oxy)hydroxides that are associated with significant amounts of hazardous metal(loid)s including Cu, Ni, Co, Zn, As and Pb in the oxidized zone, which is limited to a depth of about 1.5 mbgs in Parc B. Results of amplicon sequencing of 16S rRNA genes show significant abundances of Fe- and S-oxidizing bacteria and S-reducing bacteria but no presence of Fe-reducing bacteria. Solid-phase analyses indicate a low amount of total C in the oxidized tailings. These findings suggest that EWT technique can be an effective reclamation method for Mine Principale tailings if use in conjunction with another suitable method to address potential low-quality drainage resulting from the inducement of reducing conditions post EWT application.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.074
Threshold uncertainty score0.146

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0010.000
Scholarly communication0.0010.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.232
Teacher spread0.218 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2024
Admission routes1
Has abstractyes

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