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Record W7052609044

Staking out the Tm Proton drip-line with mass spectrometry and using electrons to sympathetically cool ions inside a penning trap

2023· dissertation· en· W7052609044 on OpenAlexaboutno aff

Bibliographic record

VenueMspace (University of Manitoba) · 2023
Typedissertation
Languageen
FieldChemistry
TopicMass Spectrometry Techniques and Applications
Canadian institutionsnot available
Fundersnot available
KeywordsPenning trapMass spectrometryIonAtomic massAccelerator mass spectrometryIon trapIsotopeElectron
DOInot available

Abstract

fetched live from OpenAlex

Energy differences in nuclei are paramount to understanding the nuclear systems far from stability, their rare decay modes, and trends in their relative stability. Modern ion trapping techniques such as Penning Trap Mass Spectrometry (PTMS), and Multiple Reflection Time Of Flight Mass Spectrometry (MRTOF-MS) have enabled the precision measurement of energy trends in even very short-lived nuclei, by allowing their masses to be measured. Such nuclei can be generated in large quantities at TRIUMF's Isotope Separator and Accelerator (ISAC), and TRIUMF's Ion Trap for Atomic and Nuclear science (TITAN) specializes in measuring the masses of the short-lived species produced at ISAC using an array of ion traps. This thesis describes measurements of the masses of neutron-deficient lanthanide elements produced at the ISAC facility at TRIUMF in Vancouver, Canada using the TITAN Multiple Reflection Time-Of-Flight (MR-TOF) mass spectrometer. The goal of these measurements was to extend the known existence of the N=82 shell closure up to Yb (Z=70), and to experimentally determine the location of the proton drip-line in Tm (Z=69). Mass measurements of 150Yb, 151Yb, and 153Yb confirm the continued existence of the N=82 shell closure. Additionally, new mass measurements of 149Tm and 150Tm were performed, as well as a re-measurement of 149Er that provides a correction to the literature value as published in the 2020 Atomic Mass Evaluation. Together, these mass data points provide the first experimental confirmation that 149Tm is the first proton-unbound species in the Tm isotopic chain. Furthermore, a new technique intended for rapidly cooling highly-charged ions (HCIs) produced via charge-breeding in TITAN's Electron Beam Ion Trap (EBIT) is experimentally tested. This technique involves sympathetically cooling the ions using free electrons, and holds the promise of cooling HCIs on a time-scale of seconds or less for studies with either short-lived or stable species. Technical challenges to implementing sympathetic cooling are discussed, and evidence for fast, electron-facilitated cooling of singly-charged species is presented.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.007

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.000
Science and technology studies0.0010.001
Scholarly communication0.0010.001
Open science0.0010.001
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0020.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.022
GPT teacher head0.250
Teacher spread0.228 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2023
Admission routes1
Has abstractyes

Explore more

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