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Record W7053669400

X-ray Absorption Spectroscopy and Powder X-ray Diffraction Studies on Green Energy Materials

2022· dissertation· en· W7053669400 on OpenAlexfundno aff

Bibliographic record

VenueThe Atrium (University of Guelph) · 2022
Typedissertation
Languageen
FieldChemical Engineering
TopicAnalytical Chemistry and Sensors
Canadian institutionsnot available
FundersMcGill UniversityCanadian Light Source
KeywordsGrapheneDopantHydrogenBattery (electricity)CathodeHydrogen storageOxideBoron oxideNanoparticle
DOInot available

Abstract

fetched live from OpenAlex

A world relying on green energy systems is on the horizon. This study focuses on the improvement of novel material components for two green energy solutions: Li-ion battery cathodes and a hydrogen storage system for hydrogen fuel cells. Li2Fe0.5Mn0.5SiO4 has been proposed as a potential new Li-ion battery cathode material due to its inexpensive cost, safety, and high theoretical capacity, however, structural changes during charge and discharge have been seen to affect its longevity. Additionally, a promising hydrogen fuel cell material of palladium (Pd) nanoparticles on a reduced graphene oxide (rGO) substrate have shown to be a good material for hydrogen storage. Interestingly, doping the rGO with a dopant has altered the Pd nanoparticle formation, increasing capacity (3-fold in the case of a boron dopant). Therefore, synchrotron-based X-ray absorption spectroscopy and powder X-ray diffraction were used to understand the structural properties of these materials to further improve them.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.004
Threshold uncertainty score0.012

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0020.001
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0040.002

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.236
Teacher spread0.222 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2022
Admission routes1
Has abstractyes

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