Synthesis of fluoroaryl functionalized organic-inorganic hybrid glasses for integrated optics
Bibliographic record
Abstract
Fluorinated organic-inorganic hybrid polymers have attracted interest over the last decade for their potential in guided wave optics.Some examples include tunable optical filters, switches, splitters, directional couplers, and modulators.Our study focuses on the synthesis and polymerization of a series of alkoxysilane monomers derivatized with different fluorinated functionalities.These monomers were prepared with a view to have a well defined refractive index, optical transparency, optical loss, mechanical flexibility, thermal stability and ease of processing.Hydrolysis and condensation experiments are performed on these monomers with different H 2 O:Si molar ratios to monitor the formation of siloxane backbones from fluoroaryl functionalized alkoxysilanes through the sol-gel process.These results are examined by NMR spectroscopy.A non-hydrolytic route to organically modified low-OH Ti/Si hybrid polymers is also studied.These polymers are synthesized by the use of boric acid for hydrolysis and titanium ethoxide, along with fluoroaryl functionalized alkoxysilane precursors for condensation.Homogenous films are made from the sol phase fluids and photolithographic experiments are conducted to fabricate waveguides.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.001 |
| Meta-epidemiology (narrow) | 0.001 | 0.001 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.001 | 0.001 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".