Bifunctional Resins Applications to the Synthesis of Insect Sex Attractants
Bibliographic record
Abstract
A 2f crosslinked divinylbenzene-styrene copolymer, incorporating benzoyl chloride groups, was used to monoprotect the symmetrical diol l,l0-decanediol.The corresponding monotrityl ether and cir-10-tetradecenJ-ol were prepared by this system, the latter by a Wittig reaction of a polymer-bound ylide with an aldehyde in the solution phase.A series of bifunctionalized resins containing proximally located trityl alcohol and benzoic acid groups was prepared in an attempt to prepare diol linked to the polymer via both a trityl ether and a benzoate linkage.It was established that these polymers bound l,l0-decanediol exclusively at one end only.Polymers, containing both trityl alcohol and benzoic acid groups in a random array or polymers containing proximally located trityl alcohol groups, gave mixtures of both monoprotected and doubly protected diol.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".