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Record W7082634368 · doi:10.5194/bg-22-4823-2025

Can atmospheric chemistry deposition schemes reliably simulate stomatal ozone flux across global land covers and climates?

2025· article· en· W7082634368 on OpenAlexaff

Bibliographic record

VenueBiogeosciences · 2025
Typearticle
Languageen
FieldComputer Science
TopicGeochemistry and Geologic Mapping
Canadian institutionsEnvironment and Climate Change Canada
FundersDeutsche Forschungsgemeinschaft
KeywordsOzoneTropospheric ozoneStomatal conductanceLand coverVegetation (pathology)Flux (metallurgy)Deposition (geology)TroposphereCanopy conductance

Abstract

fetched live from OpenAlex

Over the past few decades, ozone risk assessments for vegetation have evolved two methods based on stomatal O 3 flux. However, substantial uncertainties remain in accurately simulating these fluxes. Here, we investigate stomatal O 3 fluxes across various land cover types worldwide simulated by six established deposition models. Hourly O 3 concentration and meteorological data at nine sites were extracted from the Tropospheric Ozone Assessment Report (TOAR) database, a comprehensive global collection of measurements, for the model simulations. The models estimated reasonable O 3 deposition (0.5–0.8 cm s −1 in summer), which is mostly in agreement with the literature. Simulations of canopy conductance showed differences that varied by land cover type with correlation coefficients of 0.75, 0.80, and 0.85 for forests, crops, and grasslands among the models. Differences between models were primarily influenced by soil moisture and vapour pressure deficit, depending on each model's specific structure. Across models, the range of O 3 damage simulations at each site was most consistent for crops (6 to 11 mmol O 3 m −2 ), followed by forests (3 to 19.5 mmol O 3 m −2 ) and grasslands (7 to 33 mmol O 3 m −2 ). The median estimate across models aligns well with the literature at the sites most vulnerable to O 3 damage. Overall, this study represents a critical first step in developing and evaluating tools for broad-scale assessment of O 3 impacts on vegetation within the framework of TOAR phase II.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: Simulation or modeling
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.033
Threshold uncertainty score0.065

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.001
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0010.001
Open science0.0010.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.243
Teacher spread0.237 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2025
Admission routes1
Has abstractyes

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