Bibliographic record
Abstract
A specially designed photoelectrochemical cell, with a flat Pyrex window at the bottom for detection of the light generated from the working electrode, was used for all the electrochemical and ECL measurements. A Pt disk embedded in a glass tube was used as the working electrode (0.03 cm2), a Pt wire as the counter electrode, and an Ag wire for the quasi-reference electrode. Silole solutions were prepared with 0.1 M tetrabutylammonium perchlorate (TBAP) as the supporting electrolyte and with 3.0 mL CH2Cl2 as the solvent (Sure-Sealed, Aldrich, Mississauga ON) in an inert environment glovebox. About 1.0 mg of each silole was used. The final concentration of the solution was determined through NMR by comparison of the exact amount of TBAP with the unknown amount of sample. The loaded cell was sealed with an air-tight Teflon cap. Voltammetric ECL curves were obtained using an electrochemical workstation (CH-610A, CH
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.002 | 0.004 |
| Meta-epidemiology (narrow) | 0.002 | 0.001 |
| Meta-epidemiology (broad) | 0.002 | 0.001 |
| Bibliometrics | 0.003 | 0.003 |
| Science and technology studies | 0.002 | 0.000 |
| Scholarly communication | 0.002 | 0.002 |
| Open science | 0.004 | 0.002 |
| Research integrity | 0.002 | 0.002 |
| Insufficient payload (model declined to judge) | 0.837 | 0.654 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; the direct Gemma label and the distilled Codex classifier agree on what is shown here.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".