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Record W7096517924

Comparison with HPLC

2014· article· en· W7096517924 on OpenAlexaboutno aff

Bibliographic record

Venuenot available
Typearticle
Languageen
FieldChemistry
TopicAnalytical chemistry methods development
Canadian institutionsnot available
Fundersnot available
KeywordsCartridgeAnalyteElutionAcetonitrileHigh-performance liquid chromatographyGas chromatographyNitrateExtraction (chemistry)
DOInot available

Abstract

fetched live from OpenAlex

Abstract: An analytical method for the determination of nitroaromatic, nitramine, and nitrate ester explosives and co-contaminants in water was developed based on SPE (solid-phase extraction) and GC-ECD (gas chromato-graph-electron capture detector). Water samples are pre-concentrated using either cartridge or disk SPE followed by elution with acetonitrile. The acetonitrile extract is com-patible with both liquid and gas chromatography, thereby allowing direct comparison of concentration estimates obtained by different methods of determination. Quanti-tative GC analyses were obtained by using deactivated direct-injection-port liners, short wide-bore capillary col-umns, and high linear carrier gas velocities. Recoveries from spiked samples were 90 % or greater for each of the nitroaromatics and nitrate esters, and greater than 70% for nitramines and amino-nitrotoluenes. Estimates of analyte concentrations in well-water extracts from military sites in the United States and Canada analyzed by GC-How to get copies of CRREL technical publications:

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.007
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Methods · Consensus signal: Methods
Teacher disagreement score0.044
Threshold uncertainty score0.146

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0020.007
Meta-epidemiology (narrow)0.0020.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0030.002
Science and technology studies0.0010.001
Scholarly communication0.0020.002
Open science0.0020.001
Research integrity0.0020.002
Insufficient payload (model declined to judge)0.0440.040

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.033
GPT teacher head0.319
Teacher spread0.286 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreMethods

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2014
Admission routes1
Has abstractyes

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