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Record W7133013262

Flash Graphene Reinforced, Flexible Polyurethane Foam: Synthesis and Characterization

2022· dissertation· W7133013262 on OpenAlexfundno aff
Sophie Kiddell

Bibliographic record

VenueTSpace · 2022
Typedissertation
Language
FieldMaterials Science
TopicThermal properties of materials
Canadian institutionsnot available
FundersUniversity of Toronto
KeywordsExfoliation jointGrapheneUltimate tensile strengthComposite numberPolyurethaneFlash (photography)Compressive strengthPorosityThermal expansion
DOInot available

Abstract

fetched live from OpenAlex

Graphene nanoplatelets (GNP) are currently mass-produced by mechanical exfoliation of graphite, however, Flash Joule Heating (FJH) is a relatively sustainable, cost effective, and efficient alternative. In this work, the reinforcing abilities of industrially produced Flash Graphene (FG) in flexible polyurethane foam (FPUF) are evaluated. Three types of FG with different structure and morphology are characterized and used to produce FPUF composites. A composite containing commercial, exfoliated GNP was also prepared for comparison. It was shown that 0.025 wt.% FG improved the thermal expansion coefficient of FPUF by 47%. FG composites also demonstrated higher sound absorption at low frequency relative to neat FPUF. The tensile strength and compressive modulus of all composites also increased by 16-26% and 33-37% respectively. Furthermore, FPUF reinforced with FG showed similar or enhanced properties compared to the GNP composite. Overall, FG improved thermal and acoustic performance of FPUF without deteriorating the mechanical properties. This supports the use of FG as a sustainable, low-cost alternative to exfoliated or CVD-grown GNP in porous polymer composites.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.002

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.020
GPT teacher head0.287
Teacher spread0.267 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2022
Admission routes1
Has abstractyes

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