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Record W7135306687

Tritium Removal from CANDU Reactors

2024· report· W7135306687 on OpenAlexaboutno aff
Ella Siefken, Jason Lu, Phuong Ngo

Bibliographic record

VenueScholarly Commons (University of Pennsylvania) · 2024
Typereport
Language
Field
Topic
Canadian institutionsnot available
Fundersnot available
KeywordsTritiumHeavy waterDistillationTritiated waterElectrolysisFusion powerAir separationIsotope separation
DOInot available

Abstract

fetched live from OpenAlex

Within the next 50 years, the global demand for tritium will increase with the startup of fusion reactors, while the global supply (currently estimated at 25 kg) slowly dwindles due to its short half-life. Heavy water moderator from CANDU reactors is the only large scale source of tritium that can meet the rising demand. Only two tritium removal facilities are in operation worldwide, while the development of a third is uncertain. Currently, at the Bruce Nuclear Generation Station in Ontario, Canada, the tritiated heavy water is stored and transported to the Darlington Tritium Removal Facility, posing logistical challenges and risks of radioactive exposure during storage and transport. We propose the implementation of a tritium removal facility at the Bruce Nuclear Generation Station to continuously extract tritium from heavy water moderator from the four Bruce C units currently in the early stages of development. The heavy water would undergo electrolysis before being cooled to cryogenic temperatures of about 26–27 K and fed through a cryogenic distillation cascade that would produce gaseous tritium of 99.9% purity at a rate of 178 grams per year. Continuous tritium extraction would also maintain the radioactivity of the CANDU reactor moderator under 10 Ci/kg, an essential benchmark for reactor and environmental safety. Compared to existing tritium removal facilities, this process presents three novel advantages: 1) Direct electrolysis pre-treatment that foregoes the use of complex catalysts; 2) A thermally linked design that utilizes helium refrigerant to provide heating and cooling duty; 3) Optimized cryogenic distillation system that provides tritium product of higher purity that other similar processes. Assuming a tritium sale price of $30,000 per gram and a plant lifetime of 35 years, the tritium removal process presented is not profitable, with an ROI of -6.13% in the third production year and a negative IRR. However, this process design is highly valuable as tritium prices are expected to surge in the next decade as fusion plants reach technological readiness and require tritium to fuel fusion reactors.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.005
metaresearch head score (Gemma)0.002
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Science and technology studies, Scholarly communication, Open science, Research integrity, Insufficient payload (model declined to judge)
Consensus categoriesMeta-epidemiology (narrow), Science and technology studies, Research integrity, Insufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: Not applicable
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.400
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0050.002
Meta-epidemiology (narrow)0.0030.005
Meta-epidemiology (broad)0.0060.004
Bibliometrics0.0060.006
Science and technology studies0.0020.003
Scholarly communication0.0030.010
Open science0.0080.006
Research integrity0.0050.015
Insufficient payload (model declined to judge)0.0110.024

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.049
GPT teacher head0.253
Teacher spread0.204 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designNot applicable
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2024
Admission routes1
Has abstractyes

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