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Airborne Observations and Modeling Comparison of Global Inorganic Aerosol Acidity

2022· article· W7138942749 on OpenAlexaboutno aff
Benjamin A. Nault, Pedro Campuzano-Jost, Douglas A. Day, D. S. Jo, Jason C. Schroder, Hannah M. Allen, R. Bahreini, Huisheng Bian, Donald R. Blake, Mian Chin, Simon L. Clegg, Peter R. Colarco, John D. Crounse, M. J. Cubison, P. F. DeCarlo, Jack E. Dibb, Glenn S. Diskin, Alma Hodžić, Weiwei Hu, Joseph M. Katich, John K. Kodros, Agnieszka Kupc, F. D. Lopez-Hilfiker, E. A. Marais, A. M. Middlebrook, J. Andrew Neuman, J. A. Nowak, B. B. Palm, F. Paulot, J. L. Pierce, G. P. Schill, E. Scheuer, J. A. Thornton, K. Tsigaridis, P. O. Wennberg, C. J. Williamson, J. A. Teijeiro Jimenez

Bibliographic record

VenueUniversity of New Hampshire Scholars Repository (University of New Hampshire at Manchester) · 2022
Typearticle
Language
FieldEarth and Planetary Sciences
TopicAtmospheric chemistry and aerosols
Canadian institutionsnot available
Fundersnot available
KeywordsAerosolSpectrometerMass spectrometryChemical compositionPhotometerMixing ratioParticle (ecology)ParticulatesSoot

Abstract

fetched live from OpenAlex

This dataset provides observations collected during eleven airborne campaigns from 2006–2017 and associated input and output from nine widely used chemical transport models (CTMs). The airborne campaigns include ARCTAS-A, ARCTAS-B, ATom-1 and ATom-2, CalNex, DC3, INTEX-B, KORUS-AQ, MILAGRO, SEAC4RS, and WINTER, and they sampled mainly tropospheric air over the conterminous U.S. and the state of Alaska, Mexico, Canada, Greenland, and South Korea and remote areas over the Arctic, Pacific, Southern, and Atlantic Oceans. The CTMs are the AM4.1, CCSM4, GEOS-5, GEOS-Chem TOMAS, GEOS-Chem v10, GEOS-Chem v12, GISS-MATRIX, GISS-ModelE, and TM4-ECPL-F, and the output includes sulfate, nitrate, temperature, specific humidity, mixing ratio of ammonium, the volume mixing ratio of nitric acid, surface pressure, gas-phase ammonia, gas-phase nitric acid, pressure, total ammonium, etc. The observations were collected in-situ from a variety of instruments, including the Aerosol Microphysical Properties (AMP), HR Aerodyne Aerosol Mass Spectrometer (AMS), CIT Chemical Ionization Mass Spectrometer (CIMS), diode laser hygrometer (DLH), a mist chamber/ion chromatography system (MC/IC), Particle Analysis by Laser Mass Spectrometer (PALMS), Single Particle Soot Photometer (SP2), and UCI Whole Air Sampler (WAS). In-situ data also include latitude, longitude, and pressure. These observations were used to investigate how aerosol pH and ammonium balance change from polluted to remote regions, such as over oceans, and were compared to predictions from the CTMs.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.068
Threshold uncertainty score0.136

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.001
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0010.001
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.042
GPT teacher head0.215
Teacher spread0.173 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2022
Admission routes1
Has abstractyes

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