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Record W7162024156 · doi:10.82308/49605

Role of surfactants in kraft pulping processes

2010· dissertation· en· W7162024156 on OpenAlexaboutno aff
Magda Akadiri

Bibliographic record

Venuenot available
Typedissertation
Languageen
FieldEngineering
TopicLignin and Wood Chemistry
Canadian institutionsnot available
Fundersnot available
KeywordsKraft paperPenetration (warfare)Penetration rateBlack liquorKraft processMicellePulmonary surfactant

Abstract

fetched live from OpenAlex

Laboratory testing, using the penetration instrument developed at McGill University, was conducted in order to determine the surfactants effective at improving the kraft pulping liquor penetration into aspen heartwood during the first stages of impregnation. Five surfactants, one anionic (Sodium dodecyl benzene sulfonate from Sigma-Aldrich), and four non-ionic (TRITON X-100 and X-114, TERGITOL 15-S-7, all three from Dow Chemicals, and BUSPERSE 47 from Buckman Laboratories) were tested at their critical micelle concentration. The surfactants were used either individually or as blends of one anionic and one non-ionic surfactants. Different combinations were also tested in a 4 to 1 volume ratio of white and black liquor solution. The effectiveness of the surfactants was determined according to two methods, the qualitative analysis, based on the highest liquor absorption at a specific time, and the rate method that uses the highest penetration rate at each of the four phases of the absorption. Individually, TRITON X-100, BUSPERSE 47 and SDBS were effective according to the rate analysis. Moreover, regarding the blends, except for those involving a mixture of TERGITOL 15-S-7 and black liquor, all combinations of surfactants improved the penetration of the liquor. The best performance was achieved with the blend of SDBS and black liquor.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.003
Threshold uncertainty score0.006

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0010.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.003
GPT teacher head0.202
Teacher spread0.199 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2010
Admission routes1
Has abstractyes

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