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Liquid-liquid Extraction of Iron (III) from Hydrochloric Acid Solutions by Tributyl Phosphate.

2002· article· en· W86625808 on OpenAlex
Taichi Sato

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueShigen-to-Sozai · 2002
Typearticle
Languageen
FieldEngineering
TopicExtraction and Separation Processes
Canadian institutionsQueen's University
Fundersnot available
KeywordsTributyl phosphateHydrochloric acidChemistryExtraction (chemistry)Aqueous solutionBenzenePhosphateInorganic chemistryNuclear chemistryLiquid–liquid extractionChromatographyOrganic chemistry

Abstract

fetched live from OpenAlex

The extraction of iron (III) from hydrochloric acid solutions has been investigated using tributyl phosphate (TBP) in benzene under different conditions. The organic extracts were examined by infrared and ultraviolet absorption spectroscopies. It was found that with increasing the concentration of aqueous hydrochloric acid solutions, the distribution coefficient increased steeply at above 2-3 mol dm-3 HCl. Consequently, the following equilibrium equation is proposed for the extraction of iron (III) from hydrochloric acid solutions by TBP: FeCl3(aq) + HCl(aq) + 3TBP(org) ⇔ HFeCl4·3TBP(org).

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.184
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0030.002

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.019
GPT teacher head0.240
Teacher spread0.221 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it