MétaCan
Menu
Back to cohort
Record W936110144

Nitration of Calixcrown 6 Influence on Extracting Abilities. Use of Cesium Salts for Detection of Crown Ether Macrocycles with the Electrospray Ionization Mass Spectrometry Technique

2002· article· en· W936110144 on OpenAlexaff
Christopher K. Jankowski

Bibliographic record

VenuePolish Journal of Chemistry · 2002
Typearticle
Languageen
FieldChemistry
TopicMass Spectrometry Techniques and Applications
Canadian institutionsUniversité de Moncton
Fundersnot available
KeywordsChemistryElectrospray ionizationCrown etherNitrationMass spectrometryElectrosprayCaesiumExtractive electrospray ionizationElectrospray mass spectrometryIonizationEtherChromatographyOrganic chemistryIonProtein mass spectrometry
DOInot available

Abstract

fetched live from OpenAlex

Two organic synthetic reactions - mononitration and phosphorylation of crown-6 compounds were performed under Cs + cation monitoring via in situ complexation using electrospray ionization mass spectrometry (ESI-MS). Formation of Cs + complexes is a rapid analytical tool for characterization of complex reaction mixtures.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.023
Threshold uncertainty score0.558

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.242
Teacher spread0.228 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations12
Published2002
Admission routes1
Has abstractyes

Explore more

Same venuePolish Journal of ChemistrySame topicMass Spectrometry Techniques and ApplicationsFrench-language works237,207