Carbon Paper Electrodes Modified with Bismuth for Enhancing the Performance of Vanadium Redox Flow Batteries
Notice bibliographique
Résumé
Redox flow batteries (RFBs) are a promising technology for grid scale stationary energy storage to complement renewable energy systems. Although RFBs have a relatively low energy density, they offer important benefits such as long lifetime, decoupled energy and power, high round-trip efficiency, scalability and design flexibility, fast response and low environmental impacts. These benefits make them superior to many other stationary energy storage technologies [1-3]. The vanadium RFB (VRFB) is the most widely used RFB in industry for grid scale energy storage and for integration of renewable energy generation systems [4]. However, due to their slow redox reaction rates, their performance and stability are limited and VRFBs would thus benefit from enhancement of the electrode kinetics [5]. Various catalysts have been employed to improve the redox reaction rates [5-6]. Bismuth is considered a suitable candidate due to its good reactivity with oxygen, low toxicity, relatively low cost and comparable catalytic properties to other metal competitors [5, 7-8]. In this study, we present a novel modified VRFB electrode composed of carbonized bismuth-polyaniline (Bi-PANI) on a thermally-treated carbon paper substrate. The battery performance was evaluated in a 5 cm 2 flow cell using a ‘zero-gap’ design with a 1.6 M VOSO 4 in 3 M H 2 SO 4 electrolyte. Charge-discharge of the VRFB was performed at a constant current density (ranging from 10 to 80 mA cm −2 ) with upper and lower voltage cut-offs of 1.65 and 0.8 V, respectively. Thermally treated carbon paper electrodes were tested as a comparison, and it was found that the VRFB efficiency was significantly enhanced, from 51% to 68% at a current density of 80 mA cm − 2 , due to the modification of the electrodes with Bi-PANI. The charge-discharge capacity was also improved by around 17.2%. In addition, the stability of the battery using the modified electrodes was evaluated for over 200 cycles. The improved battery performance was attributed to the catalytic effect of the Bi particles on the VO 2+ /VO 2 + and V 2+ /V 3+ redox reactions leading to a significant increase in capacity, voltage, and energy efficiency. References: [1] M. Skyllas-Kazacos, L. Cao, M. Kazacos, N. Kausar, A. Mousa, ChemSusChem. 9 (2016) 1521–1543. [2] A.K. Singh, M. Pahlevaninezhad, N. Yasri, E. Roberts, ChemSusChem. (2021). [3] M. Pahlevaninezhad, P. Leung, M. Pahlevani, F. C. Walsh, C. Ponce de Leon, and E. P. L. Roberts, Experimental and Computational Studies of Disperse Blue-1 in Organic Non-Aqueous Redox Flow Batteries, J. Power Sources, Volume 500, 15 July 2021, 229942. [4] X.Z. Yuan, C. Song, A. Platt, N. Zhao, H. Wang, H. Li, K. Fatih, D. Jang, Int. J. Energy Res. (2019). [5] S. Moon, B.W. Kwon, Y. Chung, Y. Kwon, Journal of The Electrochemical Society, 166 (12) A2602-A2609 (2019) [6] W. Lee, C. Jo, S. Youk, H. Y. Shin, J. Lee, Y. Chung, and Y. Kwon, Appl. Surf. Sci., 429, 187 (2018) [7] Z González, A. Sánchez, C. Blanco, M. Granda, R. Menéndez, and R. Santamaria, Electrochem. Commun., 13, 1379 (2011). [8] B. Li, M. Gu, Z. Nie, Y. Shao, Q. Luo, X. wei, X. Li, J. Xiao, C. Wang, V. Sprenkle, and W. Wang, Nano Lett., 13, 1330 (2013).
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Comment cette classification a été obtenuedéplier
Prédiction distillée sur la base complète
Imitation des enseignantsNi prévalence calibrée, ni vérité terrain. Validation humaine à venir. Apprise à partir de 10 348 étiquettes directes de Codex et de 10 348 étiquettes directes de Gemma. Le mode candidate est l'union des têtes enseignantes seuillées; le consensus est leur intersection. Ces sorties portent le statut machine_predicted_unvalidated et ne sont ni des étiquettes humaines ni des étiquettes directes de modèles de pointe.
Scores Codex et Gemma par catégorie
| Catégorie | Codex | Gemma |
|---|---|---|
| Métarecherche | 0,000 | 0,000 |
| Méta-épidémiologie (sens strict) | 0,000 | 0,000 |
| Méta-épidémiologie (sens large) | 0,000 | 0,000 |
| Bibliométrie | 0,000 | 0,000 |
| Études des sciences et des technologies | 0,000 | 0,000 |
| Communication savante | 0,000 | 0,000 |
| Science ouverte | 0,000 | 0,000 |
| Intégrité de la recherche | 0,000 | 0,000 |
| Charge utile insuffisante (le modèle a refusé de juger) | 0,000 | 0,000 |
Scores machine (provisoires)
Les deux têtes enseignantes du modèle étudiant, lues sur ce travail. Un score ordonne la base pour la relecture; il n'affirme jamais une catégorie, et le statut de validation accompagne chaque rangée tel quel.
Scores de référence d'un modèle non mature (critères de maturité non atteints, 7 itérations). Un score ordonne; il n'affirme jamais une catégorie.
score_only:v0-immature-baseline · tel quel depuis la passe de notation : score_only signifie que le nombre peut ordonner les travaux, et qu'aucune étiquette de catégorie n'en découleClassification
machine, non validéePrédiction automatique; un appel candidat d’une seule tête enseignante, pas un consensus.
Le détail, modèle par modèle et score par score, se trouve en fin de page sous « Comment cette classification a été obtenue ».