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Record W100012660 · doi:10.1021/bk-2007-0956.ch004

Measurement of Antioxidant Activity in Food and Biological Systems

2007· book-chapter· en· W100012660 on OpenAlexaff
Fereidoon Shahidi, Ying Zhong

Bibliographic record

VenueACS symposium series · 2007
Typebook-chapter
Languageen
FieldChemistry
TopicFree Radicals and Antioxidants
Canadian institutionsMemorial University of Newfoundland
Fundersnot available
KeywordsOxygen radical absorbance capacityAntioxidantChemistryDPPHOxidative stressRadicalTrolox equivalent antioxidant capacityFood scienceBiochemistryLipid oxidationCrocinTroloxOxidative phosphorylationAntioxidant capacity

Abstract

fetched live from OpenAlex

The importance of lipid oxidation and antioxidants in biological systems and foodstuff has been widely recognized. Oxidative changes involving free radicals in membrane lipids are thought to have destructive cellular effects in vivo; whereas oxidative processes in foods result in flavor and nutritional quality deterioration that may also affect their safety and wholesomeness. Antioxidants protect cells and foods against oxidative stress. Many methods have been developed for evaluating the activity of antioxidants; these may be classified into two categories. The first category measures the ability of antioxidants in inhibiting oxidation reaction in a model system by monitoring the associated changes using physical, chemical or instrumental means. Radical scavenging assays include methods based on hydrogen atom transfer (HAT) or electron transfer (ET) mechanisms. Oxygen radical absorbance capacity (ORAC), total radical trapping antioxidant parameter (TRAP) and crocin bleaching assays are the major methods that measure HAT while Trolox equivalent antioxidant capacity (TEAC), ferric reducing antioxidant power (FRAP), and DPPH assays represent ET-based methods. An overview of relevant methods for evaluating antioxidant activity with emphasis on the chemistry, basic principles involved as well as advantages and disadvantages of each assay is provided.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.005
Threshold uncertainty score0.018

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0020.002
Science and technology studies0.0000.000
Scholarly communication0.0010.001
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0050.005

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.041
GPT teacher head0.232
Teacher spread0.191 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations38
Published2007
Admission routes1
Has abstractyes

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