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Record W1023375753

光化学降解黄腐酸及其对黄腐酸-苯并(α)芘结合性质的影响

2007· article· zh· W1023375753 on OpenAlexaboutno aff
楼涛, 汪学军, 王士财

Bibliographic record

Venue地球化学 · 2007
Typearticle
Languagezh
FieldEnvironmental Science
TopicWater Quality Monitoring and Analysis
Canadian institutionsnot available
Fundersnot available
KeywordsComputer science
DOInot available

Abstract

fetched live from OpenAlex

在不同照射时间、pH和溶解氧浓度下,研究了从加拿大魁北克省Rimouski河提取的黄腐酸(RRFA)在模拟太阳光照射过程中对苯并(α)芘结合性质的影响。结果表明,RRFA经模拟太阳光照射后,其与苯并(α)芘的结合系数K0c下降。光化过程中RRFA的相对分子质量或SUVA270与‰。之间有良好的指数回归关系。在pH4.1~8.0范围内,以光照后的pH条件下测定照射样品的K0c,K0c平均下降47.4%±17.4%;以光照前的pH条件下测定照射样品的K0c,K0c平均下降48.7%±16.9%。溶解氧浓度的升高能加速RRFA的光氧化降解过程,与相应的未照射样品相比,空气饱和与氧气饱和条件下照射后的K0c分别下降30%和74%,氮气饱和条件下照射后的K0c升高122%。

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.008
Threshold uncertainty score0.026

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.001
Bibliometrics0.0010.001
Science and technology studies0.0010.001
Scholarly communication0.0020.003
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0080.003

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.023
GPT teacher head0.274
Teacher spread0.250 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2007
Admission routes1
Has abstractyes

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