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Record W1130800187 · doi:10.1520/stp10258s

Terrestrial Toxicity Testing with Volatile Substances

2000· book-chapter· en· W1130800187 on OpenAlexaff
GL Stephenson, Juliska Princz, Nicola Koper, PG Miasek

Bibliographic record

Venuenot available
Typebook-chapter
Languageen
FieldEnvironmental Science
TopicToxic Organic Pollutants Impact
Canadian institutionsImperial Oil (Canada)University of AlbertaUniversity of Guelph
Fundersnot available
KeywordsToxicityEnvironmental chemistryEnvironmental scienceChemistryOrganic chemistry

Abstract

fetched live from OpenAlex

The toxicity of volatile hydrocarbons to terrestrial organisms is currently being investigated. It was found that toxicity test methods required procedural modification during test soil preparation to minimize the loss of the test substance due to volatilization. A series of tests was initiated with an artificial and field-collected reference soil to investigate alternative test-soil, preparation, methodologies for evaluating motor gasoline (mogas) as it predominantly contains highly volatile low-end carbon components (⩽C5–C13). The proposed approaches to minimize volatilization losses included the application of mogas at concentrations sufficiently high to accommodate the percentage lost during test soil preparation; the modification of test soil preparation methods; and the modification of the nature of test units. The analyses of benzene, toluene, ethylbenzene, xylene (BTEX) compounds, total purgeable hydrocarbons (TPuH), total extractable hydrocarbons (TEH), and total petroleum hydrocarbons (TPH) from soil samples quantified the losses of these mogas constituents at each stage of preparation. The constituents of the mogas were found to volatilize at different rates and the losses were to some extent, concentration dependent. Amending test soils at higher concentrations than required for an adverse effect compensated for the rate of the losses due to volatilization. Significant amounts of the mogas were lost regardless of the methods used to prepare the test soils. Alternative “closed” (minimized air exchange) test units were considered useful and acceptable, as they optimized exposure of the test organism to mogas and did not compromise their survival. The test methods developed to assess the toxicity of mogas in terrestrial organisms may be equally applicable to the toxicity testing of other highly volatile substances.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Methods · Consensus signal: none
Teacher disagreement score0.002
Threshold uncertainty score0.006

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.021
GPT teacher head0.213
Teacher spread0.192 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designNot applicable
Domainnot available
GenreMethods

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2000
Admission routes1
Has abstractyes

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