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Record W1164865416

The water-sediment interactions for Hyalella azteca exposed to uranium-spiked or contaminated sediments and different overlying water chemistries

2009· dissertation· en· W1164865416 on OpenAlexfundaboutno aff
L.C. Alves

Bibliographic record

VenueUWSpace (University of Waterloo) · 2009
Typedissertation
Languageen
FieldChemistry
TopicRadioactive element chemistry and processing
Canadian institutionsnot available
FundersNatural Sciences and Engineering Research Council of CanadaUniversity of Waterloo
KeywordsHyalella aztecaSedimentUraniumEnvironmental chemistryContaminationEnvironmental scienceGeologyChemistryEcologyGeomorphologyBiologyAmphipodaMetallurgy
DOInot available

Abstract

fetched live from OpenAlex

In comparison with other metals such as Cd, Cu, Pb, Ni, and Zn, little is known about uranium (U) toxicity to Hyalella azteca. There is even no national U water or sediment quality guideline yet for the protection of aquatic life in Canada, despite Canada being home to some of the biggest U producers in the world. In this context, the aim of this research was to determine the toxic effects of U concentrations in the water and sediment to H. azteca, and if these relationships can be modelled. This thesis demonstrated that U bioaccumulation was mainly via the water phase rather than the sediment phase. It showed that U bioaccumulation measurements in H. azteca were more reliable indicators of U toxicity than U concentrations in the water or sediment. A water-bioaccumulation saturation model was satisfactory at describing this relationship. Overlying water chemistry was found not only to influence U bioaccumulation and toxicity in the H. azteca but also the desorption of U in the sediment into the overlying water. A water-sediment partitioning saturation model was also satisfactory at explaining these interactions. 
\n\t Both body size and gut-content had an overall effect on U bioaccumulation in H. azteca exposed to water-only U concentrations in soft water. A saturation model was used not only to estimate the effect of gut-content on U bioaccumulation, but to predict the uptake and elimination rate constants for H. azteca exposed to water-only U concentrations.
\n\tA field study was conducted to determine if the saturation models developed and applied in the laboratory could be used in the field to quantify U bioavailability, bioaccumulation and toxicity to H. azteca. Unfortunately, U concentrations in the water and sediment were below concentrations needed to validate these models. However, toxicity, not related to U concentrations in the field, was observed at some field sites.
\n\tOverall this thesis not only encourages more work on U toxicity to H. azteca, but provides significant data and models to be used by risk assessors and regulators in the development of U water and sediment quality guidelines in the protection of aquatic environments in Canada.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.408
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0010.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.233
Teacher spread0.219 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2009
Admission routes2
Has abstractyes

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