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Record W1539620966 · doi:10.5772/21192

Transport of Ultradispersed Catalytic Particles Through Bitumen at Upgrading Temperatures

2011· book-chapter· en· W1539620966 on OpenAlexafffund
Herbert Loría, Pedro Pereira‐Almao

Bibliographic record

VenueInTech eBooks · 2011
Typebook-chapter
Languageen
FieldEngineering
TopicElectrohydrodynamics and Fluid Dynamics
Canadian institutionsUniversity of Calgary
FundersUniversity of CalgaryConocoPhillips
KeywordsAsphaltMaterials scienceCatalysisChemical engineeringEnvironmental scienceComposite materialChemistryEngineeringOrganic chemistry

Abstract

fetched live from OpenAlex

Mass transfer and deposition of fine particles in cylindrical channels has received considerable attention for a long time due to its practical significance and direct application in industry. For example, this knowledge is helpful in aerosol classification and its deposition under electrical fields, formation of deposits in heat exchangers and pipelines, hydrodynamic field chromatography, thrombus formation in organs and, many other areas Recently, this phenomenon has gained particular importance on the dispersion of ultradispersed catalysts for heavy crude oil and bitumen hydroprocessing due to its practical significance and direct application Ultradispersed catalysts have been studied for heavy oil and bitumen hydroprocessing as an alternative for typical supported catalysts. An advantage when comparing ultradispersed catalysts to supported ones, in the case of heavy oil and bitumen hydroprocessing, is that the former could be easily incorporated into the reaction media to flow together with the feedstock to be treated, in this manner residence times can be longer than those conventionally used for hydroprocessing Recent publications (Loria et al., 2009b(Loria et al., , 2009c Time-dependent, two and three-dimensional convective-dispersive models, which simulated the transient deposition and suspension of ultradispersed particles immersed in viscous media inside a horizontal cylinder, were developed, solved and experimentally validated. In addition, a study on the effect of the fluid medium properties over the dispersion coefficient was performed. The dispersion coefficient is a proportionality constant that serves to quantify the particle concentration due to convection and dispersion and should be expressed as a function of the properties of the fluid medium The solution of the previously mentioned models provides a particle concentration profile along the horizontal channel, as well as information regarding the critical particle size that allows particles to remain suspended in the fluid medium enclosed in this geometry. This knowledge can be applied in the previously referred ultradispersed catalysis of heavy crude oils and bitumen. In these systems, it is important to ensure that catalytic particles remain suspended in the fluid medium in order to make use of their catalytic activity and also, to www.intechopen.com

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Other · Consensus signal: none
Teacher disagreement score0.871
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.195
Teacher spread0.182 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2011
Admission routes2
Has abstractyes

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