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Sol-Gel Derived Single Layer Zeolite-MgF2 Composite Antireflective Coatings with Improved Mechanical Properties on Polycarbonate

2014· article· en· W1543407513 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

venuePublished in a venue whose home country is Canada.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueJournal of Coating Science and Technology · 2014
Typearticle
Languageen
FieldMaterials Science
TopicSilicone and Siloxane Chemistry
Canadian institutionsnot available
FundersUniversity of Hyderabad
KeywordsMaterials scienceAnti-reflective coatingPolycarbonateComposite numberComposite materialCoatingZeoliteLayer (electronics)Surface roughnessRefractive indexPorosityOrganic chemistryChemistry

Abstract

fetched live from OpenAlex

Single layer antireflective coatings with good optical and mechanical properties are difficult to be obtained on temperature sensitive substrates like plastics. This challenge has been taken up in the present study. Single layer MgF2 and for the first time, zeolite 4Å and zeolite 4Å - MgF2 composite antireflective coatings were generated by a wet chemical route on flat polycarbonate sheets and characterized for their reflectance, surface roughness, thickness, porosity, surface morphology and scratch hardness by haze measurement. Autoclaving and boiling water treatment under microwave irradiation were used in case of MgF2 sols and zeolite/zeolite-MgF2 coatings respectively. Pure MgF2 coatings deposited after autoclaving of the MgF2 sol yielded a low refractive index of 1.28 and an average reflectance of 1.9% vis-à-vis 9.7% reflectance for an uncoated polycarbonate substrate over the wavelength range of 400-1100 nm. Single layer zeolite coatings after a brief treatment in boiling water under microwave irradiation yielded a reflectance of 5.1%. A composite zeolite-MgF2 coating exhibited a reflectance of 2.8% and the percentage change in haze after crockmeter testing in case of the composite coating was lower than that of a pure MgF2 coating. This implied that the composite layer had improved mechanical properties combined with good optical properties and could be suitable for practical applications.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.003
Threshold uncertainty score0.447

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.015
GPT teacher head0.236
Teacher spread0.221 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it