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Record W1554204980 · doi:10.1002/14356007.a20_181.pub2

Phthalic Acid and Derivatives

2007· other· en· W1554204980 on OpenAlexaff
Peter M. Lorz, Friedrich K. Towae, Walter Enke, Rudolf Jäckh, Naresh Bhargava, Wolfgang Hillesheim

Bibliographic record

VenueUllmann's Encyclopedia of Industrial Chemistry · 2007
Typeother
Languageen
FieldEnvironmental Science
TopicEffects and risks of endocrine disrupting chemicals
Canadian institutionsBASF (Canada)
Fundersnot available
KeywordsPhthalic anhydridePhthalic acidPhthalimideChemistryOrganic chemistryCatalysisPhthalonitrileXyleneBenzene

Abstract

fetched live from OpenAlex

Abstract The article contains sections titled: 1. Phthalic Acid 2. Phthalic Anhydride 2.1. Physical Properties 2.2. Chemical Properties 2.3. Resources and Raw Materials 2.4. Production 2.4.1. Gas‐Phase Oxidation 2.4.1.1. Catalyst and Reaction Mechanism 2.4.1.2. Apparatus and Important Process Steps in the Gas‐Phase Oxidation ofo‐Xylene 2.4.2. Fluidized‐Bed Oxidation 2.4.3. Liquid‐Phase Oxidation ofo‐Xylene 2.5. Environmental Protection 2.6. Quality Specifications and Analysis 2.7. Economic Aspects 2.8. Storage and Transportation 2.9. Uses 3. Phthalimide 3.1. Properties 3.2. Production 3.2.1. Production from Phthalic Anhydride and Ammonia 3.2.2. Production from Phthalic Anhydride and Urea 3.2.3. Production fromo‐Xylene 3.3. Uses 4. Phthalonitrile 4.1. Properties 4.2. Production 4.2.1. Production fromo‐Xylene 4.2.2. Production from Phthalic Acid Derivatives 4.3. Uses 5. Phthalates 5.1. Physical and Chemical Properties 5.2. Raw Materials 5.3. Production 5.4. Environmental Protection 5.5. Quality Specifications 5.6. Storage and Transportation 5.7. Uses 5.8. Economic Aspects 6. Toxicology 6.1. Use of and Exposure to Phthalic Acid and Derivatives 6.2. Toxicological Profiles 6.2.1 Phthalic Acid 6.2.2 Phthalic Anhydride 6.2.3 Phthalimide 6.2.4. Phthalonitrile 6.2.5. Phthalate Esters 6.2.5.1. Metabolism and Toxicokinetics 6.2.5.2. Acute Toxicity 6.2.5.3. Irritation and Sensitizing Potential 6.2.5.4. Repeated DEHP Dosing 6.2.5.5. Genotoxicity and Mutagenicity 6.2.5.6. Carcinogenicity 6.2.5.7. Reproductive Toxicity 6.2.5.8. Effects of Phthalate Esters by Groups 6.3 Risk Assessment 6.3.1 Biomonitoring and Human Exposure to Phthalate Esters 6.3.2 Carcinogenicity

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.055
Threshold uncertainty score0.183

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0010.000
Scholarly communication0.0010.001
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0550.021

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.013
GPT teacher head0.295
Teacher spread0.282 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations117
Published2007
Admission routes1
Has abstractyes

Explore more

Same venueUllmann's Encyclopedia of Industrial ChemistrySame topicEffects and risks of endocrine disrupting chemicalsFrench-language works237,207