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Record W1571600242 · doi:10.5402/2012/272751

Swelling of Elastomers in Solutions of <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" id="M1"><mml:mrow><mml:msub><mml:mrow><mml:mtext>TiO</mml:mtext></mml:mrow><mml:mtext>2</mml:mtext></mml:msub></mml:mrow></mml:math> Nanoparticles

2012· article· en· W1571600242 on OpenAlexafffund
Ludwig Vinches, Gérald Perron, Patricia I. Dolez, Kevin J. Wilkinson, Stéphane Hallé

Bibliographic record

VenueISRN Polymer Science · 2012
Typearticle
Languageen
FieldMaterials Science
TopicPolymer Nanocomposites and Properties
Canadian institutionsCTT Group (Canada)Université de MontréalÉcole de Technologie Supérieure
FundersInstitut de Recherche Robert-Sauvé en Santé et en Sécurité du TravailÉcole de technologie supérieure
KeywordsElastomerSwellingMaterials scienceAlgorithmPolymerNatural rubberComputer scienceComposite material

Abstract

fetched live from OpenAlex

Elastomers used in protective gloves can be sensitive to the action of solvents used to disperse commercial solutions of nanoparticles. These effects may include the swelling of the polymer, leading to a modification of its mechanical and chemical properties. Modifications to the properties of the polymer will impact the protection provided by the protective gloves. The goal of this work was therefore to study the swelling of several elastomers when exposed to commercial solutions of nanoparticles. The study involved four elastomers and three commercial solutions of colloidal titanium dioxide ( TiO2 ). Swelling was assessed by measurements of mass gain and length change. Tests were also performed with technical and ultrapure solvents corresponding to the liquid carriers. The solutions had a significant effect on the swelling of nitrile rubber, latex, and neoprene. A large mass gain was recorded for short immersion times, indicating a possible penetration of the nanoparticle liquid carrier into these elastomers. Length change measurements revealed a swelling anisotropy effect with nitrile rubber and latex in the solutions of colloidal TiO2 . No effect was measured with butyl rubber. The results show that great care must be taken when selecting protective gloves for the handling of nanoparticle dispersions.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.008

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.023
GPT teacher head0.247
Teacher spread0.224 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations9
Published2012
Admission routes2
Has abstractyes

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Same venueISRN Polymer ScienceSame topicPolymer Nanocomposites and PropertiesFrench-language works237,207