Synthesis of Self‐<scp>C</scp>rosslinkable Water‐<scp>B</scp>orne Pressure Sensitive Adhesives
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
Self‐crosslinkable acrylic pressure‐sensitive adhesives (PSAs) functionalized with 3‐isopropenyl‐α,α‐dimethylbenzyl isocyanate (TMI) are prepared by starved, seeded semi‐batch emulsion polymerization. n ‐Dodecanethiol is used as a chain transfer agent (CTA) and EF‐800 as an anionic surfactant. A three‐level factorial design (3 2 ) is performed by varying the TMI and CTA concentrations. Increasing the TMI decreases the rate of polymerization. Nonetheless, high monomer conversions and zero coagulum are observed at the end of all reactions. The latexes are used to prepare PSA films for the evaluation of tack, peel strength, and shear strength. Crosslinking reactions caused by the isocyanate groups of TMI lead to films with very high gel content, even in cases where the CTA concentration is high. As a result, shear strength is greatly improved. The same films preserve sufficient tack but display low peel strength. Empirical models of the tack and peel strength data indicate that TMI has a significant effect on these properties.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it