MétaCan
Menu
Back to cohort
Record W1594418502 · doi:10.1002/9780470027318.a9297

<scp>NMR</scp>Spectroscopy in Liquid Crystalline and Ordered Phases

2012· other· en· W1594418502 on OpenAlex
Ronald Y. Dong

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueEncyclopedia of Analytical Chemistry · 2012
Typeother
Languageen
FieldMaterials Science
TopicLiquid Crystal Research Advancements
Canadian institutionsUniversity of British Columbia
Fundersnot available
KeywordsLiquid crystalNuclear magnetic resonance spectroscopyIntermolecular forceRelaxation (psychology)SpectroscopyMoleculeChemical physicsChemistryDeuterium NMRNuclear magnetic resonance crystallographyProtonCarbon-13 NMR satelliteDeuteriumNMR spectra databaseCrystallographyMaterials scienceFluorine-19 NMRSpectral linePhysicsOrganic chemistryAtomic physicsNuclear physics

Abstract

fetched live from OpenAlex

Abstract Applications of nuclear magnetic resonance (NMR) spectroscopy as an analytical tool in liquid crystals (LCs) are surveyed. Proton, deuteron, carbon‐13, and nitrogen‐14 are commonly used as probes in solid‐state NMR of condensed phases. Their usages in LCs are discussed in some details. Complex mathematical expressions needed to interpret NMR observables (both equilibrium and dynamic properties) are kept to a minimum, and the reader can refer to original articles and books for details. As it is impossible to provide an exhaustive coverage of the literature, selective examples are chosen to highlight areas of recent interests in the study of liquid‐crystal materials, particularly thermotropics, in terms of their physics and chemistry. Orientational/positional order parameters are readily obtained in ordered liquid‐crystal phases by means of NMR. They can serve as characteristic signatures of the studied mesophases. Liquid‐crystal ordering depends on intermolecular potentials among neighboring molecules. Solutes dissolved in LC solvents are good candidates to reveal different ordering mechanisms. Nonzero spin interactions are used to determine molecular structure of large and small molecules, and/or their conformation statistics. Nuclear spin relaxation times are readily measured by means of different NMR pulse techniques and can be powerful for revealing dynamic properties of mesogens with increasing structural complexity.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.461
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0100.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.291
Teacher spread0.279 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it