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Record W1733772201

Experimental Investigation of the Al-Ca-Zn system

2013· dissertation· en· W1733772201 on OpenAlexfundno aff
Shabnam Konica

Bibliographic record

VenueSpectrum Research Repository (Concordia University) · 2013
Typedissertation
Languageen
FieldEngineering
TopicAluminum Alloy Microstructure Properties
Canadian institutionsnot available
FundersGeneral Motors of CanadaConcordia UniversityNatural Sciences and Engineering Research Council of CanadaMcGill University
KeywordsIntermetallicTernary operationIsothermal processMaterials scienceCrystallographyTernary numeral systemElectron probe microanalysisSolubilityDiffractionSolid solutionAnalytical Chemistry (journal)ChemistryThermodynamicsElectron microprobeMetallurgyPhysical chemistryAlloyPhysicsChromatography
DOInot available

Abstract

fetched live from OpenAlex

In this work, the isothermal section of the Al-Ca-Zn system has been investigated at 350°C using 5 diffusion couples and 26 key alloys. The actual compositions of the alloys are measured by inductively coupled plasma technique. Phase relations and solubility limits of the binary and ternary compounds have been determined by means of electron probe microanalysis and X-ray diffraction. In the current work, five ternary compounds have been found, three of which are reported for the first time: ternary intermetallic IM1 with the formula AlxCa8.5Zny (26≤x≤29, 62≤y≤65 at 350ºC), ternary intermetallic IM3 with the formula Al3-xCaZx (2≤x≤2.2 at 350oC) and ternary intermetallic IM5 with the formula Al2Ca9Zn3. The crystal structure information of IM1 has been studied by X-ray diffraction technique. XRD data has shown that IM1 is a solid solution that crystallizes in a cubic structure with Pm3 ̅m (221) space group having BaHg11 prototype. The homogeneity ranges of IM2 and IM4 have been determined at 350oC. Binary compounds Al14Ca13, Al2Ca, Al4Ca, CaZn2, CaZn3, CaZn5, CaZn11 and CaZn13 have extended solid solubility into the ternary system. For Al14Ca13, Al2Ca and Al4Ca, Al-atom is substituted by Zn. For CaZn2, CaZn3, CaZn5, CaZn11 and CaZn13 Zn is substituted by Al.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.041
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.017
GPT teacher head0.230
Teacher spread0.213 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2013
Admission routes1
Has abstractyes

Explore more

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