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Record W1881283992 · doi:10.1139/v2012-061

Separation of bitumen from oil sands using a switchable hydrophilicity solvent

2012· article· en· W1881283992 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.
venuePublished in a venue whose home country is Canada.

Bibliographic record

VenueCanadian Journal of Chemistry · 2012
Typearticle
Languageen
FieldChemistry
TopicPetroleum Processing and Analysis
Canadian institutionsQueen's UniversityGreenCentre Canada
FundersNatural Resources CanadaKillam TrustsNatural Sciences and Engineering Research Council of CanadaCanada Research ChairsCanadian Natural Resources Limited
KeywordsOil sandsSolventAsphaltChemistryDistillationSynthetic crudeExtraction (chemistry)Chemical engineeringPulp and paper industryPetroleumOrganic chemistryShale oilMaterials scienceComposite material

Abstract

fetched live from OpenAlex

Separation of bitumen from oil sands is far more efficient with an organic solvent than with the conventional hot water (Clark) process, but the removal of the organic solvent from the bitumen requires distillation. Distillation is problematic because of the energy cost and the need for a volatile solvent (which is therefore likely to be flammable and smog-forming). A switchable hydrophilicity solvent (SHS) is a solvent that is water-miscible in the presence of an atmosphere of CO 2 but separates from water when CO 2 is absent. Extraction of bitumen from low-grade high-fines oil sands using a SHS (CyNMe 2 ) is efficient, removing 94%–97% of the bitumen. The resulting solids (sand and clay) are dry, free-flowing, and contaminated with only 0.4 wt % of bitumen and as little as 102 ppm of the solvent. No distillation step was required to recover the solvent from the bitumen. Instead, carbonated water extraction removed the solvent from the oil. Losses of the CyNMe 2 solvent were, for the best method, 0.06 grams of solvent per gram of bitumen recovered. The method recovers more oil than the Clark process, produces cleaner solids, works with low-grade high-fines oil sands, and requires neither distillation nor a volatile solvent.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.016
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.015
GPT teacher head0.245
Teacher spread0.230 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it