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Record W1896704121 · doi:10.1002/cjce.22262

CO<sub>2</sub>‐oil saturation pressure and onset asphaltene precipitation

2015· article· en· W1896704121 on OpenAlexvenueno aff
Victor Rodrigues da Rocha Oliveira, Noemi Araújo Esquivel da Silva, Marcos Miranda Silva Souza, Sílvio A.B. Vieira de Melo, Glória Meyberg Nunes Costa

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2015
Typearticle
Languageen
FieldChemistry
TopicPetroleum Processing and Analysis
Canadian institutionsnot available
Fundersnot available
KeywordsAsphalteneBubbleBubble pointFraction (chemistry)Petroleum engineeringEnhanced oil recoverySaturation (graph theory)PrecipitationMethaneThermodynamicsCrude oilChemistryMass fractionMaterials scienceChromatographyMechanicsGeologyOrganic chemistryMeteorologyMathematics

Abstract

fetched live from OpenAlex

Partial miscible flooding using CO2 injection has been shown to be a promising method for enhanced oil recovery, but this injection could result in asphaltene precipitation, which clogs the reservoir and production equipment. Therefore, an important parameter to be monitored is the onset of asphaltene precipitation. The efficient displacement of oil by CO2 depends on a variety of factors, including phase behaviour of CO2/crude‐oil mixtures that requires an accurate description of the CO2‐oil mixture bubble pressure. Observing bubble pressure behaviour, it is possible to exactly determine the CO2 molar fraction for onset asphaltene precipitation, which is expected to occur when the selected injection pressure is equal to the bubble pressure at the same CO2 molar fraction. However, assessment of oil characterization relating CO2‐oil mixture bubble pressure and onset asphaltene precipitation has not been found in the literature and should be properly addressed. In this work, we employed the Soave‐Redlich‐Kwong equation of state and used CO2‐oil mixture bubble pressure experimental data from literature to show that the accuracy of onset asphaltene precipitation is quite affected by the binary interaction parameter between methane and C7+ fractions, and the density of this heavy fraction.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.004
Threshold uncertainty score0.008

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.199
Teacher spread0.191 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations3
Published2015
Admission routes1
Has abstractyes

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