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Record W1963797547 · doi:10.1002/app.35511

Reinforcement of soy polyol‐based rigid polyurethane foams by cellulose microfibers and nanoclays

2011· article· en· W1963797547 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueJournal of Applied Polymer Science · 2011
Typearticle
Languageen
FieldMaterials Science
TopicPolymer composites and self-healing
Canadian institutionsUniversity of Toronto
Fundersnot available
KeywordsMicrofiberPolyurethaneMaterials scienceComposite materialCelluloseThermogravimetric analysisPolyolThermal decompositionChemical engineeringChemistry

Abstract

fetched live from OpenAlex

Abstract Water‐blown rigid polyurethane foams from soy‐based polyol were prepared and their structure–property correlations investigated. Cellulose microfibers and nanoclays were added to the formulations to investigate their effect on morphology, mechanical, and thermal properties of polyurethane foams. Physical properties of foams, including density and compressive strength, were determined. The cellular morphologies of foams were analyzed by SEM and X‐ray micro‐CT and revealed that incorporation of microfibers and nanoclays into foam altered the cellular structure of the foams. Average cell size decreased, cell size distribution narrowed and number fractions of small cells increased with the incorporation of microfibers and nanoclays into the foam, thereby altering the foam mechanical properties. The morphology and properties of nanoclay reinforced polyurethane foams were also found to be dependent on the functional groups of the organic modifiers. Results showed that the compressive strengths of rigid foams were increased by addition of cellulose microfibers or nanoclays into the foams. Thermogravimetric analysis (TGA) was used to characterize the thermal decomposition properties of the foams. The thermal decomposition behavior of all soy‐based polyurethane foams was a three‐step process and while the addition of cellulose microfibers delayed the onset of degradation, incorporation of nanoclays seemed to have no significant influence on the thermal degradation properties of the foams as compared to the foams without reinforcements. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.004
Threshold uncertainty score0.746

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.213
Teacher spread0.201 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it