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Thermally Stable Multilamellar Structure of DNA/Cationic Lipid Complex in the Bulk State

2014· article· en· W1963810079 on OpenAlexvenueno aff
Ching-Mao Wu, Szu-Yin Lin

Bibliographic record

VenueJournal of Applied Solution Chemistry and Modeling · 2014
Typearticle
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicDNA and Nucleic Acid Chemistry
Canadian institutionsnot available
FundersIndustrial Technology Research Institute
KeywordsCationic polymerizationChemistryDNACrystallographyChemical physicsBiophysicsPolymer chemistryBiochemistryBiology

Abstract

fetched live from OpenAlex

The effect of temperature on the two types of multilamellar structures, LI and LII, formed by the complexes of DNA with a cationic lipid, cholesteryl 3β-N-(dimethylamionethyl) carbamate (DC-Chol), in the bulk state has been investigated by small angle X-ray scattering (SAXS). LI phase composing of A-DNA intercalated between the lipid bilayers with tilted tails was formed at lower lipid-to-base pair molar ratio (x < 2), while LII phase consisting of B-DNA bound to untilted lipid was formed at x > 2. In addition to the differences in lipid packing state and DNA conformation, these two lamellar phases also displayed different thermal stability. LI phase was highly thermally stable as its interlamellar distance remained essentially unperturbed even after the denaturation of A-DNA in the complex at elevated temperature. By contrast, the interlamellar distance of LII phase decreased with increasing temperature due to the release of bound water and B-DNA denaturation.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.018
Threshold uncertainty score0.374

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.233
Teacher spread0.221 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2014
Admission routes1
Has abstractyes

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