Controlling the Morphologies of Organometallic Block Copolymers in the 3-Dimensional Spatial Confinement of Colloidal and Inverse Colloidal Crystals
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Bibliographic record
Abstract
A detailed study of the three-dimensional (3-D) confinement of polystyrene- block -poly(ferrocenylethylmethylsilane) ( PS- b -PFS ) diblock copolymers in silica colloidal crystals and inverse silica colloidal crystals is reported. Inversion of the silica colloidal crystal lattice with PS- b -PFS is confirmed by scanning electron microscopy and optical spectroscopy. Additionally, the modification of the silica surfaces in the inverse colloidal crystals using hydroxy-terminated PS and PFS is established. The 3-D confined morphologies of a lamella-forming and a cylinder-forming PS- b -PFS diblock copolymer are subsequently investigated. The manipulation of the 3-D confined morphology of cylinder-forming PS- b -PFS is demonstrated by deliberate alteration of its wetting interaction with the surface-modified colloidal crystal templates. Unprecedented 3-dimensional block copolymer morphology transitions are elucidated.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.001 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it