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Record W1971203822 · doi:10.2113/gscanmin.39.2.309

THE DISTRIBUTION OF Cr BETWEEN BASALTIC MELT AND CHROMIAN SPINEL AS AN OXYGEN GEOBAROMETER

2001· article· en· W1971203822 on OpenAlexaffvenue
A. Poustovetov, P. L. Roeder

Bibliographic record

VenueThe Canadian Mineralogist · 2001
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicGeological and Geochemical Analysis
Canadian institutionsQueen's University
Fundersnot available
KeywordsSpinelBasaltGeochemistryGeologyOxygenMineralogyChemistryPaleontology

Abstract

fetched live from OpenAlex

A thermodynamic model of Cr distribution between chromian spinel and basaltic melt has been developed using the [Sack & Ghiorso (1991)][1] thermodynamic model for chromian spinel and an equation analogous to that of [Sack et al. (1980)][2] to calculate the Cr oxidation state in the melt. The model has been calibrated using published experimental data on the composition of coexisting chromian spinel and basaltic melt. The model can be used either to calculate the oxygen fugacity, f (O2), of magmas saturated with chromian spinel, to predict the Cr content of the melt, or to calculate the oxidation state of Cr in the melt. The f (O2) values calculated for a set of natural lavas (primitive MORB and a Hawaiian pumice) using the method show good agreement with f (O2) values calculated from measured values of Fe3+/Fe2+ in the melt. An EXCEL spreadsheet for calculating log f (O2) using composition of glass and chromian spinel is available from the authors upon request. [1]: #ref-23 [2]: #ref-22

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.161
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.018
GPT teacher head0.212
Teacher spread0.194 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations38
Published2001
Admission routes2
Has abstractyes

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