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Record W1971975401 · doi:10.2136/vzj2008.0044

New Observations of Gas‐Phase Expansion above a Dense Nonaqueous Phase Liquid Pool

2009· article· en· W1971975401 on OpenAlexafffund
Kevin G. Mumford, James E. Smith, Sarah Dickson‐Anderson

Bibliographic record

VenueVadose Zone Journal · 2009
Typearticle
Languageen
FieldEngineering
TopicEnhanced Oil Recovery Techniques
Canadian institutionsMcMaster University
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsDissolutionGas phasePhase (matter)Fragmentation (computing)ChemistrySoil scienceEnvironmental science

Abstract

fetched live from OpenAlex

The partitioning of volatile dense nonaqueous phase liquid (DNAPL) compounds to a discontinuous gas phase results in the repeated expansion, fragmentation, and vertical mobilization of gas clusters. This process has the potential to significantly affect the dissolution of DNAPL source zones and the characterization of DNAPL‐contaminated sites, but has not been included in common conceptual models. This study presents new observations of discontinuous gas‐phase growth above a 1,1,1‐trichloroethane pool in a two‐dimensional flow cell packed with 1.1‐mm diameter sand. In contrast to the behavior observed in coarse glass beads, these visualization results show that the gas phase evolves as a collection of macroscopic fingers, composed of multiple trapped and disconnected gas clusters, and that the growth rate of these fingers is faster at the leading edge of the DNAPL pool due to the stripping of dissolved gases. These results provide valuable information for the incorporation of discontinuous gas phases in our evolving conceptual models of DNAPL source zones.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.200
Threshold uncertainty score0.938

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.018
GPT teacher head0.278
Teacher spread0.259 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations13
Published2009
Admission routes2
Has abstractyes

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