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Record W1972526545 · doi:10.1021/ie040134b

Some Observations on the Contraction Behavior of a Water-in-Oil Drop with Attached Solids

2004· article· en· W1972526545 on OpenAlex
Samuel O. Asekomhe, Raymond Chiang, Jacob H. Masliyah, Janet A.W. Elliott

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueIndustrial & Engineering Chemistry Research · 2004
Typearticle
Languageen
FieldMaterials Science
TopicPickering emulsions and particle stabilization
Canadian institutionsUniversity of Alberta
FundersNatural Sciences and Engineering Research Council of CanadaCanadian Space Agency
KeywordsDrop (telecommunication)EmulsionSilicone oilAdsorptionMaterials scienceChemical engineeringContact angleAsphaltPressure dropChemical physicsComposite materialChemistryThermodynamicsOrganic chemistry

Abstract

fetched live from OpenAlex

One of the factors responsible for the high stability of water-in-bitumen or water-in-crude oil emulsions is the presence of a complex adsorbed layer of material at the water−oil interface. However, except for its role as a steric barrier, little is known about the nature and activity of this layer. Studying a macroscopic drop, on which interfacial adsorbed particles can be controlled and directly observed, will provide useful information that can be linked to the behavior of real emulsion systems. A macroscopic drop prepared using silicone oil, water, and silica particles was studied in this work. The results of this study indicate that the presence of slightly hydrophobic particles at the water−oil interface is sufficient to cause the interface crumpling that has been observed with water drops in crude oil or bitumen subjected to interfacial area reduction. For crumpling to occur, the particles need to remain strongly attached to the interface (i.e., have intermediate contact angles) as the drop interfacial area is reduced. The observed crumpling behavior is clearly reversible.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.034
Threshold uncertainty score0.264

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.144
GPT teacher head0.338
Teacher spread0.194 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it