Dynamics of Crystal Structure Formation in Spin-Coated Colloidal Films
Bibliographic record
Abstract
The spin-coating of colloidal suspensions is an inherently nonequilibrium process that gives rise to highly reproducible, but polycrystalline, films with different symmetries depending on experimental parameters. In this study, we explore the transient dynamics of evaporative colloid spin-coating for the first time, via a combination of high-speed imaging, atomic force microscopy, static photography, and scanning electron microscopy. As the wet colloidal film thins and dries, we observe several symmetry transitions, while at the same time remarkably, the thinning rate (in nondimensional time units) collapses to one universal curve for all rotation rates. We correlate static and dynamic measures of crossovers in ordering regimes, and obtain an estimate of the evaporation rate in the late stage of drying. We conclude that the thinning dynamics controls the local volume fraction and stress profiles, which in turn drives the structural transitions.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".