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Record W1973820022 · doi:10.1364/ao.45.005270

Correction of instrument line shape in Fourier transform spectrometry using matrix inversion

2006· article· en· W1973820022 on OpenAlexaff
Raphaël Desbiens, Jérôme Genest, Pierre Tremblay, Jean‐Pierre Bouchard

Bibliographic record

VenueApplied Optics · 2006
Typearticle
Languageen
FieldChemistry
TopicSpectroscopy and Chemometric Analyses
Canadian institutionsUniversité Laval
Fundersnot available
KeywordsInversion (geology)OpticsFourier transformSpectrometerPhysicsAlgorithmComputer scienceGeology

Abstract

fetched live from OpenAlex

A novel matrix inversion approach is proposed to correct several contributions to the instrument line shape (ILS) of a Fourier transform spectrometer. The matrix formalism for the ILS is first quickly reviewed. Formal inversion of the ILS matrix is next discussed, along with its limitations. The stability of the inversion process for large field-of view- (FOV-) limited and highly off-axis line shapes is investigated. The effect of inversion on the noise that is present in the spectrum is also presented. Use of classical iterative inversion methods, coupled with efficient synthesis algorithms, is proposed as a way to drastically speed up the inversion process. The method is applied to correct HBr spectra obtained from a laboratory spectrometer that has an adjustable field of view. ILSS from six FOVs are brought to the same spectral axis and to the same ideal sinc shape.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.070
Threshold uncertainty score0.652

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.258
Teacher spread0.244 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations11
Published2006
Admission routes1
Has abstractyes

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