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Record W1973990326 · doi:10.2118/171076-ms

The Role of Asphaltenes in Emulsion Formation for Steam Assisted Gravity Drainage (SAGD) and Expanding Solvent - SAGD (ES-SAGD)

2014· article· en· W1973990326 on OpenAlexaboutno aff
Taniya Kar, Matthew J. Williamson, Berna Hasçakir

Bibliographic record

Venuenot available
Typearticle
Languageen
FieldChemistry
TopicPetroleum Processing and Analysis
Canadian institutionsnot available
FundersTexas A and M University
KeywordsAsphalteneSteam-assisted gravity drainageEmulsionSolventOil sandsTolueneChemistryHexaneAsphaltChemical engineeringZeta potentialProduced waterWettingFourier transform infrared spectroscopyPetroleum engineeringChromatographyGeologyMaterials scienceOrganic chemistryComposite material

Abstract

fetched live from OpenAlex

Abstract Steam Assisted Gravity Drainage (SAGD) and Expanding Solvent SAGD (ES-SAGD) have previously been compared and ES-SAGD has shown improved oil recovery with lower energy and water requirements and significant oil upgrading. However, solvent selection is the key factor which determines the performance of ES-SAGD due to the asphaltene-solvent interaction. The change in asphaltene stability with the solvent type can have several drawbacks during ES-SAGD. Stable emulsion formation is one of these problems which have not been investigated thoroughly for ES-SAGD. In this study, we characterized both water-in-oil and oil-in-water type of emulsions originating from SAGD, SAGD with n-hexane and SAGD with n-hexane and toluene mixture experiments. These three experiments were conducted on 8.65 °API Canadian bitumen with 34.3 wt% asphaltene content. Structural changes in produced oil, produced water, and spent rock samples were analyzed with Fourier Transform Infrared (FTIR) spectroscopy. Emulsions in produced oil and water samples were determined with microscopic images. The differences in emulsions were interpreted with the wettability change determined on spent rock samples. Moreover, the asphaltene fraction of produced oil samples is further analyzed with FTIR and zeta potential measurements. For produced oil, the greatest asphaltene content with more severe emulsion formations were detected on the sample originating from SAGD. In terms of stability, because the asphaltenes originating from both ES-SAGD experiments have higher zeta potential values, lower emulsion stability has been observed for the produced oil originating from ES-SAGD. In summary, the role of asphaltenes on emulsion formation has been studied for SAGD and ES-SAGD for bitumen extraction. ES-SAGD with asphaltene soluble solvents leads to the formation of less stable emulsions.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.358
Threshold uncertainty score0.352

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.252
Teacher spread0.242 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations29
Published2014
Admission routes1
Has abstractyes

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