Conformation Effects on the Dissociation of Ionized Polymers
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
The collision-induced dissociation (CID) of a series of oligomer chain lengths of four polymer samples have been quantified according to their observed total relative fragment ion abundances. The CID mass spectra of oligomers of ionized poly(methyl methacrylate) (PMMA), with three different types of end groups and polystyrene (PS), were obtained at fixed center-of-mass collision energies and collision numbers. For the PMMA polymers, the total fragment ion abundance increases with increasing chain length, consistent with an increase in internal energy deposition with the size of the ion. A discontinuity in the increase in total fragment ion abundance appears to correspond with a change in conformation of the polymer ions from linear (at short chain lengths) to cyclic (at long chain lengths). Ionized PS does not exhibit this change in conformation as all chain lengths show compact structures and accordingly the total fragment ion abundance does not change with increasing chain length.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.003 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it