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Record W1982853298 · doi:10.1029/2009jd012135

Total hydrogen budget of the equatorial upper stratosphere

2010· article· en· W1982853298 on OpenAlexaff
Jonathan E. Wrotny, Gerald E. Nedoluha, C. D. Boone, G. P. Stiller, J. P. McCormack

Bibliographic record

VenueJournal of Geophysical Research Atmospheres · 2010
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicAtmospheric Ozone and Climate
Canadian institutionsUniversity of Waterloo
FundersNational Aeronautics and Space Administration
KeywordsStratosphereMixing ratioAtmospheric sciencesAtmosphere (unit)Water vaporHydrogenAtmospheric soundingMethaneEnvironmental scienceTropopauseClimatologyChemistryMeteorologyPhysicsGeology

Abstract

fetched live from OpenAlex

Water vapor and methane mixing ratios measured by the Halogen Occultation Experiment (HALOE), the Atmospheric Chemistry Experiment (ACE), and the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) along with simulations from the NRL CHEM2D middle atmosphere model are used to study the hydrogen budget in the equatorial upper stratosphere. Multiyear time series of equatorial upper stratospheric H 2 O + 2*CH 4 show temporal variations during periods of relative long‐term stability in water vapor and methane entering the stratosphere. These variations, which are anticorrelated to CH 4 , are quasibiennial and seasonal in nature, and peak near 2 hPa with a magnitude of 3% of the H 2 O + 2*CH 4 mixing ratio. We find that the ratio of the changes in water vapor to the changes in methane is consistently >2 over the entire equatorial upper stratosphere in HALOE, ACE, and MIPAS data. Ratios of the H 2 O to CH 4 changes calculated from the CHEM2D model are similar, but slightly smaller, and the variations in H 2 O + 2*CH 4 are balanced by nearly equivalent variations in molecular hydrogen. We use this relationship to infer molecular hydrogen mixing ratios from the observations which show that its mixing ratio decreases with altitude above 5 hPa. This net loss in molecular hydrogen drives additional water vapor production so that multiyear average profiles of H 2 O + 2*CH 4 from HALOE, ACE, and MIPAS show an ∼0.4 ppmv increase between 5 hPa and 1.5 hPa, so that total hydrogen is conserved. Collectively, these results illustrate the importance of molecular hydrogen in the equatorial upper stratospheric hydrogen budget.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.143
Threshold uncertainty score0.996

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0050.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.018
GPT teacher head0.282
Teacher spread0.264 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations36
Published2010
Admission routes1
Has abstractyes

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